Pincer-(NHC)Mn(I) Complex-Catalyzed Selective α‑Alkylation of Ketones and Nitriles Using Unactivated Alkenyl Alcohols

Pincer-(NHC)Mn(I) Complex-Catalyzed Selective α‑Alkylation of Ketones and Nitriles Using Unactivated Alkenyl Alcohols

Construction of C–C bonds utilizing challenging alkenyl alcohols employing first-row transition-metal catalysts is an unexplored area. Herein, we report the α-alkylation of ketones and nitriles using unactivated alkenyl alcohols as coupling partners in the presence of a phosphine-free pincer-NHC car...

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Bibliographic Details
Main Author: Adarsha Mandal (13876919) (author)
Other Authors: Manoj Pradhan (12067271) (author), Chirantan Mitra (20473299) (author), Srabani Nandi (15451796) (author), Biswajit Sadhu (1431220) (author), Sabuj Kundu (1787752) (author)
Published: 2024
Subjects:
Biophysics
Biochemistry
Molecular Biology
Biotechnology
Sociology
Infectious Diseases
Chemical Sciences not elsewhere classified
several control experiments
green chemistry metrics
density functional theory
pincer -( nhc
nhc carbene
free pincer
wide variety
unexplored area
synthetic value
scale synthesis
row transition
reaction mechanism
practical applicability
metal catalysts
kinetic studies
important molecules
highly effective
hammett studies
coupling partners
catalytic system
alkylated products
aliphatic units
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