Pincer-(NHC)Mn(I) Complex-Catalyzed Selective α‑Alkylation of Ketones and Nitriles Using Unactivated Alkenyl Alcohols

Construction of C–C bonds utilizing challenging alkenyl alcohols employing first-row transition-metal catalysts is an unexplored area. Herein, we report the α-alkylation of ketones and nitriles using unactivated alkenyl alcohols as coupling partners in the presence of a phosphine-free pincer-NHC car...

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Bibliographic Details
Main Author:	Adarsha Mandal (13876919) (author)
Other Authors:	Manoj Pradhan (12067271) (author), Chirantan Mitra (20473299) (author), Srabani Nandi (15451796) (author), Biswajit Sadhu (1431220) (author), Sabuj Kundu (1787752) (author)
Published:	2024
Subjects:	Biophysics Biochemistry Molecular Biology Biotechnology Sociology Infectious Diseases Chemical Sciences not elsewhere classified several control experiments green chemistry metrics density functional theory pincer -( nhc nhc carbene free pincer wide variety unexplored area synthetic value scale synthesis row transition reaction mechanism practical applicability metal catalysts kinetic studies important molecules highly effective hammett studies coupling partners catalytic system alkylated products aliphatic units
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Pincer-(NHC)Mn(I) Complex-Catalyzed Selective α‑Alkylation of Ketones and Nitriles Using Unactivated Alkenyl Alcohols

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