Spent Caustic Treatment Using Advanced Oxidation Processes

A Master of Science thesis in Chemical Engineering by Mohammed Al Jabari entitled, "Spent Caustic Treatment Using Advanced Oxidation Processes," submitted in May 2012. Thesis advisor is Dr. Raafat Alnaizy. Available are both soft and hard copies of the thesis.

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Main Author: Al Jabari, Mohammed (author)
Format: doctoralThesis
Published: 2012
Subjects:
Online Access:http://hdl.handle.net/11073/4066
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author Al Jabari, Mohammed
author_facet Al Jabari, Mohammed
author_role author
dc.contributor.none.fl_str_mv Alnaizy, Raafat
Aidan, Ahmed
dc.creator.none.fl_str_mv Al Jabari, Mohammed
dc.date.none.fl_str_mv 2012-09-16T06:30:31Z
2012-09-16T06:30:31Z
2012-05
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv 35.232-2012.12
http://hdl.handle.net/11073/4066
dc.language.none.fl_str_mv en_US
dc.subject.none.fl_str_mv spent caustic
oil refineries
oxidation processes
Petroleum waste
Purification
Sewage
Oxidation
Refinery spent caustic
Purification
dc.title.none.fl_str_mv Spent Caustic Treatment Using Advanced Oxidation Processes
dc.type.none.fl_str_mv info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/doctoralThesis
description A Master of Science thesis in Chemical Engineering by Mohammed Al Jabari entitled, "Spent Caustic Treatment Using Advanced Oxidation Processes," submitted in May 2012. Thesis advisor is Dr. Raafat Alnaizy. Available are both soft and hard copies of the thesis.
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id aus_23ebf0318a751b46c96e86fe44a5ff93
identifier_str_mv 35.232-2012.12
language_invalid_str_mv en_US
network_acronym_str aus
network_name_str aus
oai_identifier_str oai:repository.aus.edu:11073/4066
publishDate 2012
repository.mail.fl_str_mv
repository.name.fl_str_mv
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spelling Spent Caustic Treatment Using Advanced Oxidation ProcessesAl Jabari, Mohammedspent causticoil refineriesoxidation processesPetroleum wastePurificationSewageOxidationRefinery spent causticPurificationA Master of Science thesis in Chemical Engineering by Mohammed Al Jabari entitled, "Spent Caustic Treatment Using Advanced Oxidation Processes," submitted in May 2012. Thesis advisor is Dr. Raafat Alnaizy. Available are both soft and hard copies of the thesis.Mixed refinery spent caustic is an industrial wastewater that is generated from oil refineries. Spent caustic undergo two treatment steps, chemical oxidation followed by biological post treatment step. The goal of chemical oxidation is to drop the contamination concentration to a level that biological treatment can take place. The maximum contaminants concentration, which can be measured by chemical oxygen demand, that biological treatment can be applied, is 1,000 ppm. Advanced oxidation processes, in specific, fenton's reaction is tested to check if the method can be applied to spent caustic treatment. The research is divided into two parts, bench scale study followed by pilot plant study. The goal of bench scale study is to treat spent caustic to achieve a final chemical oxygen demand of 1,000 ppm with minimum hydrogen peroxide to chemical oxygen demand ratio possible by manipulating other factors affecting chemical oxygen demand removal. It was found out that the highest chemical oxygen demand removal achieved is 97% at optimum hydrogen peroxide to ferrous sulfate to chemical oxygen demand mass ratio of 3.8/2.1/1. Moving on to the pilot plant study, the objective of the pilot plant study is to check if fenton's process can be applied in large scale. The best result obtained is a final chemical oxygen demand of 525 ppm while operating at hydrogen peroxide to ferrous sulfate to chemical oxygen demand mass ratio of 3.5/1.6/1.College of EngineeringDepartment of Chemical EngineeringMaster of Science in Chemical Engineering (MSChE)Alnaizy, RaafatAidan, Ahmed2012-09-16T06:30:31Z2012-09-16T06:30:31Z2012-05info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisapplication/pdf35.232-2012.12http://hdl.handle.net/11073/4066en_USoai:repository.aus.edu:11073/40662025-06-26T12:33:14Z
spellingShingle Spent Caustic Treatment Using Advanced Oxidation Processes
Al Jabari, Mohammed
spent caustic
oil refineries
oxidation processes
Petroleum waste
Purification
Sewage
Oxidation
Refinery spent caustic
Purification
status_str publishedVersion
title Spent Caustic Treatment Using Advanced Oxidation Processes
title_full Spent Caustic Treatment Using Advanced Oxidation Processes
title_fullStr Spent Caustic Treatment Using Advanced Oxidation Processes
title_full_unstemmed Spent Caustic Treatment Using Advanced Oxidation Processes
title_short Spent Caustic Treatment Using Advanced Oxidation Processes
title_sort Spent Caustic Treatment Using Advanced Oxidation Processes
topic spent caustic
oil refineries
oxidation processes
Petroleum waste
Purification
Sewage
Oxidation
Refinery spent caustic
Purification
url http://hdl.handle.net/11073/4066