Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation
The thermal conductivities of selected deep eutectic solvents (DESs) were determined using the modified transient plane source (MTPS) method over the temperature range from 295 K to 363 K at atmospheric pressure. The results were found to range from 0.198 W·m⁻¹·K⁻¹ to 0.250 W·m⁻¹·K⁻¹. Various empiri...
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2020
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| Online Access: | http://hdl.handle.net/11073/19782 |
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| _version_ | 1864513437538713600 |
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| author | Ibrahim, Taleb |
| author2 | Sabri, Muhammad Ashraf Abdel-Jabbar, Nabil Nancarrow, Paul Mjalli, Farouq Sabri AlNashef, Inas |
| author2_role | author author author author author |
| author_facet | Ibrahim, Taleb Sabri, Muhammad Ashraf Abdel-Jabbar, Nabil Nancarrow, Paul Mjalli, Farouq Sabri AlNashef, Inas |
| author_role | author |
| dc.creator.none.fl_str_mv | Ibrahim, Taleb Sabri, Muhammad Ashraf Abdel-Jabbar, Nabil Nancarrow, Paul Mjalli, Farouq Sabri AlNashef, Inas |
| dc.date.none.fl_str_mv | 2020-09-06T05:57:23Z 2020-09-06T05:57:23Z 2020 |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | Ibrahim, T.H.; Sabri, M.A.; Abdel Jabbar, N.; Nancarrow, P.; Mjalli, F.S.; AlNashef, I. Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation. Molecules 2020, 25, 3816. 1420-3049 http://hdl.handle.net/11073/19782 10.3390/molecules25173816 |
| dc.language.none.fl_str_mv | en |
| dc.publisher.none.fl_str_mv | MDPI |
| dc.relation.none.fl_str_mv | https://doi.org/10.3390/molecules25173816 |
| dc.subject.none.fl_str_mv | Thermal conductivity Deep eutectic solvent Choline chloride Ionic liquids Group contribution |
| dc.title.none.fl_str_mv | Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation |
| dc.type.none.fl_str_mv | Peer-Reviewed Published version info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | The thermal conductivities of selected deep eutectic solvents (DESs) were determined using the modified transient plane source (MTPS) method over the temperature range from 295 K to 363 K at atmospheric pressure. The results were found to range from 0.198 W·m⁻¹·K⁻¹ to 0.250 W·m⁻¹·K⁻¹. Various empirical and thermodynamic correlations present in literature, including the group contribution method and mixing correlations, were used to model the thermal conductivities of these DES at different temperatures. The predictions of these correlations were compared and consolidated with the reported experimental values. In addition, the thermal conductivities of DES mixtures with water over a wide range of compositions at 298 K and atmospheric pressure were measured. The standard uncertainty in thermal conductivity was estimated to be less than ± 0.001 W·m⁻¹·K⁻¹ and ± 0.05 K in temperature. The results indicated that DES have significant potential for use as heat transfer fluids. |
| format | article |
| id | aus_5bb966d4aa82dcc3ab63cd12f8d2df43 |
| identifier_str_mv | Ibrahim, T.H.; Sabri, M.A.; Abdel Jabbar, N.; Nancarrow, P.; Mjalli, F.S.; AlNashef, I. Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation. Molecules 2020, 25, 3816. 1420-3049 10.3390/molecules25173816 |
| language_invalid_str_mv | en |
| network_acronym_str | aus |
| network_name_str | aus |
| oai_identifier_str | oai:repository.aus.edu:11073/19782 |
| publishDate | 2020 |
| publisher.none.fl_str_mv | MDPI |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| spelling | Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and EstimationIbrahim, TalebSabri, Muhammad AshrafAbdel-Jabbar, NabilNancarrow, PaulMjalli, Farouq SabriAlNashef, InasThermal conductivityDeep eutectic solventCholine chlorideIonic liquidsGroup contributionThe thermal conductivities of selected deep eutectic solvents (DESs) were determined using the modified transient plane source (MTPS) method over the temperature range from 295 K to 363 K at atmospheric pressure. The results were found to range from 0.198 W·m⁻¹·K⁻¹ to 0.250 W·m⁻¹·K⁻¹. Various empirical and thermodynamic correlations present in literature, including the group contribution method and mixing correlations, were used to model the thermal conductivities of these DES at different temperatures. The predictions of these correlations were compared and consolidated with the reported experimental values. In addition, the thermal conductivities of DES mixtures with water over a wide range of compositions at 298 K and atmospheric pressure were measured. The standard uncertainty in thermal conductivity was estimated to be less than ± 0.001 W·m⁻¹·K⁻¹ and ± 0.05 K in temperature. The results indicated that DES have significant potential for use as heat transfer fluids.MDPI2020-09-06T05:57:23Z2020-09-06T05:57:23Z2020Peer-ReviewedPublished versioninfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfIbrahim, T.H.; Sabri, M.A.; Abdel Jabbar, N.; Nancarrow, P.; Mjalli, F.S.; AlNashef, I. Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation. Molecules 2020, 25, 3816.1420-3049http://hdl.handle.net/11073/1978210.3390/molecules25173816enhttps://doi.org/10.3390/molecules25173816oai:repository.aus.edu:11073/197822024-08-22T12:05:25Z |
| spellingShingle | Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation Ibrahim, Taleb Thermal conductivity Deep eutectic solvent Choline chloride Ionic liquids Group contribution |
| status_str | publishedVersion |
| title | Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation |
| title_full | Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation |
| title_fullStr | Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation |
| title_full_unstemmed | Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation |
| title_short | Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation |
| title_sort | Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation |
| topic | Thermal conductivity Deep eutectic solvent Choline chloride Ionic liquids Group contribution |
| url | http://hdl.handle.net/11073/19782 |