Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing
A novel triazene-anthracene-based fuorescent aminal linked porous organic polymer (TALPOP) was prepared via metal free-Schif base polycondensation reaction of 9,10-bis-(4,6-diamino-S-triazin2-yl)anthracene and 2-furaldehyde. The polymer has exceptional chemical and thermal stabilities and exhibit go...
محفوظ في:
| المؤلف الرئيسي: | |
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| مؤلفون آخرون: | , , , |
| التنسيق: | article |
| منشور في: |
2020
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| الموضوعات: | |
| الوصول للمادة أونلاين: | http://hdl.handle.net/11073/19797 |
| الوسوم: |
إضافة وسم
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| _version_ | 1864513443679174656 |
|---|---|
| author | Sabri, Muhammad Ashraf |
| author2 | Al-Sayah, Mohammad Sen, Susan Ibrahim, Taleb El-Kadri, Oussama |
| author2_role | author author author author |
| author_facet | Sabri, Muhammad Ashraf Al-Sayah, Mohammad Sen, Susan Ibrahim, Taleb El-Kadri, Oussama |
| author_role | author |
| dc.creator.none.fl_str_mv | Sabri, Muhammad Ashraf Al-Sayah, Mohammad Sen, Susan Ibrahim, Taleb El-Kadri, Oussama |
| dc.date.none.fl_str_mv | 2020-10-01T10:58:37Z 2020-10-01T10:58:37Z 2020 |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | Sabri, M.A., Al-Sayah, M.H., Sen, S. et al. Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing. Sci Rep 10, 15943 (2020). https://doi.org/10.1038/s41598-020-72697-x 2045-2322 http://hdl.handle.net/11073/19797 10.1038/s41598-020-72697-x |
| dc.language.none.fl_str_mv | en_US |
| dc.publisher.none.fl_str_mv | Nature |
| dc.relation.none.fl_str_mv | https://doi.org/10.1038/s41598-020-72697-x |
| dc.subject.none.fl_str_mv | Environmental impact Materials science Polymer chemistry |
| dc.title.none.fl_str_mv | Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing |
| dc.type.none.fl_str_mv | Peer-Reviewed Published version info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | A novel triazene-anthracene-based fuorescent aminal linked porous organic polymer (TALPOP) was prepared via metal free-Schif base polycondensation reaction of 9,10-bis-(4,6-diamino-S-triazin2-yl)anthracene and 2-furaldehyde. The polymer has exceptional chemical and thermal stabilities and exhibit good porosity with Brunauer–Emmett–Teller surface area of 401 m2 g−1. The combination of such porosity along with the highly conjugated heteroatom-rich framework enabled the polymer to exhibit exceptional iodine vapor uptake of up to 314 wt % and reversible iodine adsorption in solution. Because of the inclusion of the anthracene moieties, the TALPOP exhibited excellent detection sensitivity towards iodine via forescence quenching with Ksv value of 2.9 × 103 L mol−1. The cost effective TALPOP along with its high uptake and sensing of iodine, make it an ideal material for environmental remediation. |
| format | article |
| id | aus_679f34991a28ff9760835f69a3d05b78 |
| identifier_str_mv | Sabri, M.A., Al-Sayah, M.H., Sen, S. et al. Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing. Sci Rep 10, 15943 (2020). https://doi.org/10.1038/s41598-020-72697-x 2045-2322 10.1038/s41598-020-72697-x |
| language_invalid_str_mv | en_US |
| network_acronym_str | aus |
| network_name_str | aus |
| oai_identifier_str | oai:repository.aus.edu:11073/19797 |
| publishDate | 2020 |
| publisher.none.fl_str_mv | Nature |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| spelling | Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensingSabri, Muhammad AshrafAl-Sayah, MohammadSen, SusanIbrahim, TalebEl-Kadri, OussamaEnvironmental impactMaterials sciencePolymer chemistryA novel triazene-anthracene-based fuorescent aminal linked porous organic polymer (TALPOP) was prepared via metal free-Schif base polycondensation reaction of 9,10-bis-(4,6-diamino-S-triazin2-yl)anthracene and 2-furaldehyde. The polymer has exceptional chemical and thermal stabilities and exhibit good porosity with Brunauer–Emmett–Teller surface area of 401 m2 g−1. The combination of such porosity along with the highly conjugated heteroatom-rich framework enabled the polymer to exhibit exceptional iodine vapor uptake of up to 314 wt % and reversible iodine adsorption in solution. Because of the inclusion of the anthracene moieties, the TALPOP exhibited excellent detection sensitivity towards iodine via forescence quenching with Ksv value of 2.9 × 103 L mol−1. The cost effective TALPOP along with its high uptake and sensing of iodine, make it an ideal material for environmental remediation.Nature2020-10-01T10:58:37Z2020-10-01T10:58:37Z2020Peer-ReviewedPublished versioninfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfSabri, M.A., Al-Sayah, M.H., Sen, S. et al. Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing. Sci Rep 10, 15943 (2020). https://doi.org/10.1038/s41598-020-72697-x2045-2322http://hdl.handle.net/11073/1979710.1038/s41598-020-72697-xen_UShttps://doi.org/10.1038/s41598-020-72697-xoai:repository.aus.edu:11073/197972024-08-22T12:05:58Z |
| spellingShingle | Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing Sabri, Muhammad Ashraf Environmental impact Materials science Polymer chemistry |
| status_str | publishedVersion |
| title | Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing |
| title_full | Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing |
| title_fullStr | Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing |
| title_full_unstemmed | Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing |
| title_short | Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing |
| title_sort | Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing |
| topic | Environmental impact Materials science Polymer chemistry |
| url | http://hdl.handle.net/11073/19797 |