Process simulation and analysis of a five-step copper–chlorine thermochemical water decomposition cycle for sustainable hydrogen production
A process model of a five-step copper–chlorine (Cu–Cl) cycle is developed and simulated with the Aspen Plus simulation code. Energy and mass balances, stream flows and properties, heat exchanger duties, and shaft work are determined. The primary reactions of the five-step Cu–Cl cycle are assessed in...
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2014
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| Online Access: | http://hdl.handle.net/11073/25245 |
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| _version_ | 1864513435880914944 |
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| author | Orhan, Mehmet Fatih |
| author2 | Dincer, Ibrahim Rosen, Marc |
| author2_role | author author |
| author_facet | Orhan, Mehmet Fatih Dincer, Ibrahim Rosen, Marc |
| author_role | author |
| dc.creator.none.fl_str_mv | Orhan, Mehmet Fatih Dincer, Ibrahim Rosen, Marc |
| dc.date.none.fl_str_mv | 2014 2023-05-10T07:52:10Z 2023-05-10T07:52:10Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | Orhan, M., Dincer, I., & Rosen, M. A. (2014). Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production. International Journal of Energy Research, 38(11), 1391–1402. https://doi.org/10.1002/er.3148 0363-907X http://hdl.handle.net/11073/25245 10.1002/er.3148 |
| dc.language.none.fl_str_mv | en_US |
| dc.publisher.none.fl_str_mv | Wiley |
| dc.relation.none.fl_str_mv | https://doi.org/10.1002/er.3148 |
| dc.subject.none.fl_str_mv | Hydrogen production Thermochemical water decomposition Copper–chlorine cycle Nuclear heat utilization Process simulation Optimization |
| dc.title.none.fl_str_mv | Process simulation and analysis of a five-step copper–chlorine thermochemical water decomposition cycle for sustainable hydrogen production |
| dc.type.none.fl_str_mv | Peer-Reviewed Published version info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | A process model of a five-step copper–chlorine (Cu–Cl) cycle is developed and simulated with the Aspen Plus simulation code. Energy and mass balances, stream flows and properties, heat exchanger duties, and shaft work are determined. The primary reactions of the five-step Cu–Cl cycle are assessed in terms of varying operating and design parameters. A sensitivity analysis is performed to examine the effect of parameter variations on other variables, in part to assist optimization efforts. For each cycle step, reaction heat variations with such parameters as process temperature are described quantitatively. The energy efficiency of the five-step Cu–Cl thermochemical cycle is found to be 44% on the basis of the lower heating value of hydrogen, and a parametric study of potential efficiency improvement measures is presented. |
| format | article |
| id | aus_92f51d117f1c8447f9bfe7d60399084b |
| identifier_str_mv | Orhan, M., Dincer, I., & Rosen, M. A. (2014). Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production. International Journal of Energy Research, 38(11), 1391–1402. https://doi.org/10.1002/er.3148 0363-907X 10.1002/er.3148 |
| language_invalid_str_mv | en_US |
| network_acronym_str | aus |
| network_name_str | aus |
| oai_identifier_str | oai:repository.aus.edu:11073/25245 |
| publishDate | 2014 |
| publisher.none.fl_str_mv | Wiley |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| spelling | Process simulation and analysis of a five-step copper–chlorine thermochemical water decomposition cycle for sustainable hydrogen productionOrhan, Mehmet FatihDincer, IbrahimRosen, MarcHydrogen productionThermochemical water decompositionCopper–chlorine cycleNuclear heat utilizationProcess simulationOptimizationA process model of a five-step copper–chlorine (Cu–Cl) cycle is developed and simulated with the Aspen Plus simulation code. Energy and mass balances, stream flows and properties, heat exchanger duties, and shaft work are determined. The primary reactions of the five-step Cu–Cl cycle are assessed in terms of varying operating and design parameters. A sensitivity analysis is performed to examine the effect of parameter variations on other variables, in part to assist optimization efforts. For each cycle step, reaction heat variations with such parameters as process temperature are described quantitatively. The energy efficiency of the five-step Cu–Cl thermochemical cycle is found to be 44% on the basis of the lower heating value of hydrogen, and a parametric study of potential efficiency improvement measures is presented.Ontario Research Excellence FundAtomic Energy of Canada LimitedWiley2023-05-10T07:52:10Z2023-05-10T07:52:10Z2014Peer-ReviewedPublished versioninfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfOrhan, M., Dincer, I., & Rosen, M. A. (2014). Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production. International Journal of Energy Research, 38(11), 1391–1402. https://doi.org/10.1002/er.31480363-907Xhttp://hdl.handle.net/11073/2524510.1002/er.3148en_UShttps://doi.org/10.1002/er.3148oai:repository.aus.edu:11073/252452024-08-22T12:09:05Z |
| spellingShingle | Process simulation and analysis of a five-step copper–chlorine thermochemical water decomposition cycle for sustainable hydrogen production Orhan, Mehmet Fatih Hydrogen production Thermochemical water decomposition Copper–chlorine cycle Nuclear heat utilization Process simulation Optimization |
| status_str | publishedVersion |
| title | Process simulation and analysis of a five-step copper–chlorine thermochemical water decomposition cycle for sustainable hydrogen production |
| title_full | Process simulation and analysis of a five-step copper–chlorine thermochemical water decomposition cycle for sustainable hydrogen production |
| title_fullStr | Process simulation and analysis of a five-step copper–chlorine thermochemical water decomposition cycle for sustainable hydrogen production |
| title_full_unstemmed | Process simulation and analysis of a five-step copper–chlorine thermochemical water decomposition cycle for sustainable hydrogen production |
| title_short | Process simulation and analysis of a five-step copper–chlorine thermochemical water decomposition cycle for sustainable hydrogen production |
| title_sort | Process simulation and analysis of a five-step copper–chlorine thermochemical water decomposition cycle for sustainable hydrogen production |
| topic | Hydrogen production Thermochemical water decomposition Copper–chlorine cycle Nuclear heat utilization Process simulation Optimization |
| url | http://hdl.handle.net/11073/25245 |