Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery

In this work, liposome-coated iron (III) benzene-1,3,5-tricarboxylate (Fe-BTC) metal–organic framework is examined as a promising pH/Ultrasound dual-responsive nanocarriers for doxorubicin (DOX) delivery. The successful coating of the MOF particles (Lip-Fe-BTC) with the phospholipid bilayer (PBL) wa...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Karami, Abdollah (author)
مؤلفون آخرون: Ahmed, Ahmed H.S (author), Sabouni, Rana (author), Husseini, Ghaleb (author), Al Sharabati, Miral Osama Yacoub (author), AlSawaftah, Nour Majdi (author), Paul, Vinod (author)
التنسيق: article
منشور في: 2022
الموضوعات:
الوصول للمادة أونلاين:http://hdl.handle.net/11073/25518
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author Karami, Abdollah
author2 Ahmed, Ahmed H.S
Sabouni, Rana
Husseini, Ghaleb
Al Sharabati, Miral Osama Yacoub
AlSawaftah, Nour Majdi
Paul, Vinod
author2_role author
author
author
author
author
author
author_facet Karami, Abdollah
Ahmed, Ahmed H.S
Sabouni, Rana
Husseini, Ghaleb
Al Sharabati, Miral Osama Yacoub
AlSawaftah, Nour Majdi
Paul, Vinod
author_role author
dc.creator.none.fl_str_mv Karami, Abdollah
Ahmed, Ahmed H.S
Sabouni, Rana
Husseini, Ghaleb
Al Sharabati, Miral Osama Yacoub
AlSawaftah, Nour Majdi
Paul, Vinod
dc.date.none.fl_str_mv 2022
2024-04-22T08:48:47Z
2024-04-22T08:48:47Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv Karami, A.; Ahmed, A.; Sabouni, R.; Husseini, G. A.; Al Sharabati, M.; AlSawaftah,N.; Paul, V. Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery, Colloids and Surfaces B: Biointerfaces, Volume 217, 2022, 112599, ISSN 0927-7765, https://doi.org/10.1016/j.colsurfb.2022.112599.
0927-7765
http://hdl.handle.net/11073/25518
10.1016/j.colsurfb.2022.112599
dc.language.none.fl_str_mv en_US
dc.publisher.none.fl_str_mv Elsevier
dc.relation.none.fl_str_mv https://doi.org/10.1016/j.colsurfb.2022.112599
dc.subject.none.fl_str_mv Metal–organic frameworks
Drug delivery
Ultrasound
Triggered release
Encapsulation efficiency
Doxorubicin
Fe-BTC
Liposomes
Phospholipid bilayer
dc.title.none.fl_str_mv Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery
dc.type.none.fl_str_mv Peer-Reviewed
Postprint
info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/article
description In this work, liposome-coated iron (III) benzene-1,3,5-tricarboxylate (Fe-BTC) metal–organic framework is examined as a promising pH/Ultrasound dual-responsive nanocarriers for doxorubicin (DOX) delivery. The successful coating of the MOF particles (Lip-Fe-BTC) with the phospholipid bilayer (PBL) was established by direct fusion into the synthesized liposomes. The liposome coating was verified using several techniques, including dynamic light scattering (DLS) and transmission electron microscopy (TEM). The DLS measurements showed an increase in the average particle diameter of liposomes from 150 nm to 163.1 nm for Lip-Fe-BTC particles. The Fe-BTC particles had the highest average particle diameter (287.3 nm). These results demonstrated that the PBL reduced the aggregation of the particles and improved their dispersity in the release medium. The TGA results demonstrated the MOF’s excellent thermal stability. Furthermore, the nanocarrier’s loading efficiency and capacity were determined to be ~90% and ~13.5 wt%, respectively. The in-vitro DOX release experiments demonstrated that the DOX-loaded Fe-BTC and liposome-coated Fe-BTC particles showed good pH and US dual-responsive capability, making them promising nanocarriers for drug delivery. The application of US enhanced DOX release from both Fe-BTC and liposome-coated Fe-BTC. In the case of Fe-BTC-DOX particles, the application of US enhanced the DOX release to around 38% and 67%, at pH levels of 7.4 and 5.3, respectively. Similarly, DOX release from the Lip-Fe-BTC-DOX particles reached ~35% and ~53%, at pH levels of 7.4 and 5.3, respectively. The MTT assay showed the biocompatibility and low cytotoxicity of these nanocarriers below 100 µg/ml.
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identifier_str_mv Karami, A.; Ahmed, A.; Sabouni, R.; Husseini, G. A.; Al Sharabati, M.; AlSawaftah,N.; Paul, V. Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery, Colloids and Surfaces B: Biointerfaces, Volume 217, 2022, 112599, ISSN 0927-7765, https://doi.org/10.1016/j.colsurfb.2022.112599.
0927-7765
10.1016/j.colsurfb.2022.112599
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oai_identifier_str oai:repository.aus.edu:11073/25518
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spelling Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug deliveryKarami, AbdollahAhmed, Ahmed H.SSabouni, RanaHusseini, GhalebAl Sharabati, Miral Osama YacoubAlSawaftah, Nour MajdiPaul, VinodMetal–organic frameworksDrug deliveryUltrasoundTriggered releaseEncapsulation efficiencyDoxorubicinFe-BTCLiposomesPhospholipid bilayerIn this work, liposome-coated iron (III) benzene-1,3,5-tricarboxylate (Fe-BTC) metal–organic framework is examined as a promising pH/Ultrasound dual-responsive nanocarriers for doxorubicin (DOX) delivery. The successful coating of the MOF particles (Lip-Fe-BTC) with the phospholipid bilayer (PBL) was established by direct fusion into the synthesized liposomes. The liposome coating was verified using several techniques, including dynamic light scattering (DLS) and transmission electron microscopy (TEM). The DLS measurements showed an increase in the average particle diameter of liposomes from 150 nm to 163.1 nm for Lip-Fe-BTC particles. The Fe-BTC particles had the highest average particle diameter (287.3 nm). These results demonstrated that the PBL reduced the aggregation of the particles and improved their dispersity in the release medium. The TGA results demonstrated the MOF’s excellent thermal stability. Furthermore, the nanocarrier’s loading efficiency and capacity were determined to be ~90% and ~13.5 wt%, respectively. The in-vitro DOX release experiments demonstrated that the DOX-loaded Fe-BTC and liposome-coated Fe-BTC particles showed good pH and US dual-responsive capability, making them promising nanocarriers for drug delivery. The application of US enhanced DOX release from both Fe-BTC and liposome-coated Fe-BTC. In the case of Fe-BTC-DOX particles, the application of US enhanced the DOX release to around 38% and 67%, at pH levels of 7.4 and 5.3, respectively. Similarly, DOX release from the Lip-Fe-BTC-DOX particles reached ~35% and ~53%, at pH levels of 7.4 and 5.3, respectively. The MTT assay showed the biocompatibility and low cytotoxicity of these nanocarriers below 100 µg/ml.American University of SharjahElsevier2024-04-22T08:48:47Z2024-04-22T08:48:47Z2022Peer-ReviewedPostprintinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfKarami, A.; Ahmed, A.; Sabouni, R.; Husseini, G. A.; Al Sharabati, M.; AlSawaftah,N.; Paul, V. Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery, Colloids and Surfaces B: Biointerfaces, Volume 217, 2022, 112599, ISSN 0927-7765, https://doi.org/10.1016/j.colsurfb.2022.112599.0927-7765http://hdl.handle.net/11073/2551810.1016/j.colsurfb.2022.112599en_UShttps://doi.org/10.1016/j.colsurfb.2022.112599oai:repository.aus.edu:11073/255182024-08-22T12:05:52Z
spellingShingle Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery
Karami, Abdollah
Metal–organic frameworks
Drug delivery
Ultrasound
Triggered release
Encapsulation efficiency
Doxorubicin
Fe-BTC
Liposomes
Phospholipid bilayer
status_str publishedVersion
title Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery
title_full Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery
title_fullStr Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery
title_full_unstemmed Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery
title_short Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery
title_sort Hybrid liposome/metal–organic framework as a promising dual-responsive nanocarriers for anticancer drug delivery
topic Metal–organic frameworks
Drug delivery
Ultrasound
Triggered release
Encapsulation efficiency
Doxorubicin
Fe-BTC
Liposomes
Phospholipid bilayer
url http://hdl.handle.net/11073/25518