Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production

A process model of a five-step copper–chlorine (Cu–Cl) cycle is developed and simulated with the Aspen Plus simulation code. Energy and mass balances, stream flows and properties, heat exchanger duties, and shaft work are determined. The primary reactions of the five-step Cu–Cl cycle are assessed in...

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محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Orhan, Mehmet Fatih (author)
مؤلفون آخرون: Dincer, Ibrahim (author), Rosen, Marc A. (author)
التنسيق: article
منشور في: 2014
الوصول للمادة أونلاين:http://hdl.handle.net/11073/8143
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author Orhan, Mehmet Fatih
author2 Dincer, Ibrahim
Rosen, Marc A.
author2_role author
author
author_facet Orhan, Mehmet Fatih
Dincer, Ibrahim
Rosen, Marc A.
author_role author
dc.creator.none.fl_str_mv Orhan, Mehmet Fatih
Dincer, Ibrahim
Rosen, Marc A.
dc.date.none.fl_str_mv 2014-01
2016-02-29T07:18:01Z
2016-02-29T07:18:01Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv Orhan, Mehmet, Ibrahim Dincer, and Marc A. Rosen. "Process Simulation and Analysis of a Five-Step Copper-Chlorine Thermochemical Water Decomposition Cycle for Sustainable Hydrogen Production." International Journal of Energy Research 38, no. 11 (2014): 1391-1402.
1099-114X
http://hdl.handle.net/11073/8143
10.1002/er.3148
dc.language.none.fl_str_mv en_US
dc.relation.none.fl_str_mv http://onlinelibrary.wiley.com/doi/10.1002/er.3148/abstract
dc.title.none.fl_str_mv Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production
dc.type.none.fl_str_mv info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/article
description A process model of a five-step copper–chlorine (Cu–Cl) cycle is developed and simulated with the Aspen Plus simulation code. Energy and mass balances, stream flows and properties, heat exchanger duties, and shaft work are determined. The primary reactions of the five-step Cu–Cl cycle are assessed in terms of varying operating and design parameters. A sensitivity analysis is performed to examine the effect of parameter variations on other variables, in part to assist optimization efforts. For each cycle step, reaction heat variations with such parameters as process temperature are described quantitatively. The energy efficiency of the five-step Cu–Cl thermochemical cycle is found to be 44% on the basis of the lower heating value of hydrogen, and a parametric study of potential efficiency improvement measures is presented. Copyright © 2014 John Wiley & Sons, Ltd.
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identifier_str_mv Orhan, Mehmet, Ibrahim Dincer, and Marc A. Rosen. "Process Simulation and Analysis of a Five-Step Copper-Chlorine Thermochemical Water Decomposition Cycle for Sustainable Hydrogen Production." International Journal of Energy Research 38, no. 11 (2014): 1391-1402.
1099-114X
10.1002/er.3148
language_invalid_str_mv en_US
network_acronym_str aus
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oai_identifier_str oai:repository.aus.edu:11073/8143
publishDate 2014
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spelling Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen productionOrhan, Mehmet FatihDincer, IbrahimRosen, Marc A.A process model of a five-step copper–chlorine (Cu–Cl) cycle is developed and simulated with the Aspen Plus simulation code. Energy and mass balances, stream flows and properties, heat exchanger duties, and shaft work are determined. The primary reactions of the five-step Cu–Cl cycle are assessed in terms of varying operating and design parameters. A sensitivity analysis is performed to examine the effect of parameter variations on other variables, in part to assist optimization efforts. For each cycle step, reaction heat variations with such parameters as process temperature are described quantitatively. The energy efficiency of the five-step Cu–Cl thermochemical cycle is found to be 44% on the basis of the lower heating value of hydrogen, and a parametric study of potential efficiency improvement measures is presented. Copyright © 2014 John Wiley & Sons, Ltd.2016-02-29T07:18:01Z2016-02-29T07:18:01Z2014-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfOrhan, Mehmet, Ibrahim Dincer, and Marc A. Rosen. "Process Simulation and Analysis of a Five-Step Copper-Chlorine Thermochemical Water Decomposition Cycle for Sustainable Hydrogen Production." International Journal of Energy Research 38, no. 11 (2014): 1391-1402.1099-114Xhttp://hdl.handle.net/11073/814310.1002/er.3148en_UShttp://onlinelibrary.wiley.com/doi/10.1002/er.3148/abstractoai:repository.aus.edu:11073/81432024-08-22T12:17:44Z
spellingShingle Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production
Orhan, Mehmet Fatih
status_str publishedVersion
title Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production
title_full Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production
title_fullStr Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production
title_full_unstemmed Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production
title_short Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production
title_sort Process simulation and analysis of a five-step copper-chlorine thermochemical water decomposition cycle for sustainable hydrogen production
url http://hdl.handle.net/11073/8143