Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS

Silane monolayers on silica, prepared from mono-, di-, and trichlorosilanes, are widely used in industry for surface functionalization and modification. However, unlike di- and trichlorosilanes, monochlorosilanes are particularly easy to work with because they can dimerize, but not polymerize, upon...

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محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Husseini, Ghaleb (author)
مؤلفون آخرون: Linford, Matthew R. (author), Asplund, Matthew C. (author), Peacock, Justin G. (author), Sevy, Eric T. (author)
التنسيق: article
منشور في: 2002
الموضوعات:
الوصول للمادة أونلاين:http://hdl.handle.net/11073/21332
الوسوم: إضافة وسم
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author Husseini, Ghaleb
author2 Linford, Matthew R.
Asplund, Matthew C.
Peacock, Justin G.
Sevy, Eric T.
author2_role author
author
author
author
author_facet Husseini, Ghaleb
Linford, Matthew R.
Asplund, Matthew C.
Peacock, Justin G.
Sevy, Eric T.
author_role author
dc.creator.none.fl_str_mv Husseini, Ghaleb
Linford, Matthew R.
Asplund, Matthew C.
Peacock, Justin G.
Sevy, Eric T.
dc.date.none.fl_str_mv 2002
2021-03-04T06:02:37Z
2021-03-04T06:02:37Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv Husseini, G. A., Linford, M. R., Asplund, M. C., Peacock, J., & Sevy, E. T. (2001). Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS. Surface Science Spectra, 8(4), 291-296. https://doi.org/10.1116/11.20020504
1055-5269
http://hdl.handle.net/11073/21332
10.1116/11.20020504
dc.language.none.fl_str_mv en_US
dc.publisher.none.fl_str_mv American Vacuum Society
dc.relation.none.fl_str_mv https://doi.org/10.1116/11.20020504
dc.subject.none.fl_str_mv X-ray photoelectron spectroscopy
Silane
Alkylation
Monochlorosilanes
dc.title.none.fl_str_mv Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS
dc.type.none.fl_str_mv Peer-Reviewed
Published version
info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/article
description Silane monolayers on silica, prepared from mono-, di-, and trichlorosilanes, are widely used in industry for surface functionalization and modification. However, unlike di- and trichlorosilanes, monochlorosilanes are particularly easy to work with because they can dimerize, but not polymerize, upon reaction with water. Typically, an organic solvent is used when depositing a silane monolayer. Here we show XPS spectra of monolayers of 3-glycidoxypropyldimethylethoxysilane (CAS# 17963-04-1) on silicon oxide (silicon wafer) prepared using a rapid, solvent-free approach. Reaction conditions are 100 °C for 10 min using the neat (pure) compound, and no inert atmosphere or special treatment of the compound is required.
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identifier_str_mv Husseini, G. A., Linford, M. R., Asplund, M. C., Peacock, J., & Sevy, E. T. (2001). Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS. Surface Science Spectra, 8(4), 291-296. https://doi.org/10.1116/11.20020504
1055-5269
10.1116/11.20020504
language_invalid_str_mv en_US
network_acronym_str aus
network_name_str aus
oai_identifier_str oai:repository.aus.edu:11073/21332
publishDate 2002
publisher.none.fl_str_mv American Vacuum Society
repository.mail.fl_str_mv
repository.name.fl_str_mv
repository_id_str
spelling Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPSHusseini, GhalebLinford, Matthew R.Asplund, Matthew C.Peacock, Justin G.Sevy, Eric T.X-ray photoelectron spectroscopySilaneAlkylationMonochlorosilanesSilane monolayers on silica, prepared from mono-, di-, and trichlorosilanes, are widely used in industry for surface functionalization and modification. However, unlike di- and trichlorosilanes, monochlorosilanes are particularly easy to work with because they can dimerize, but not polymerize, upon reaction with water. Typically, an organic solvent is used when depositing a silane monolayer. Here we show XPS spectra of monolayers of 3-glycidoxypropyldimethylethoxysilane (CAS# 17963-04-1) on silicon oxide (silicon wafer) prepared using a rapid, solvent-free approach. Reaction conditions are 100 °C for 10 min using the neat (pure) compound, and no inert atmosphere or special treatment of the compound is required.American Vacuum Society2021-03-04T06:02:37Z2021-03-04T06:02:37Z2002Peer-ReviewedPublished versioninfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfHusseini, G. A., Linford, M. R., Asplund, M. C., Peacock, J., & Sevy, E. T. (2001). Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS. Surface Science Spectra, 8(4), 291-296. https://doi.org/10.1116/11.200205041055-5269http://hdl.handle.net/11073/2133210.1116/11.20020504en_UShttps://doi.org/10.1116/11.20020504oai:repository.aus.edu:11073/213322024-08-22T12:04:24Z
spellingShingle Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS
Husseini, Ghaleb
X-ray photoelectron spectroscopy
Silane
Alkylation
Monochlorosilanes
status_str publishedVersion
title Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS
title_full Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS
title_fullStr Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS
title_full_unstemmed Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS
title_short Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS
title_sort Alkyl Monolayers on Silica Surfaces Prepared from Neat, Heated 3-Glycidoxypropyldimethylethoxysilane Analyzed by XPS
topic X-ray photoelectron spectroscopy
Silane
Alkylation
Monochlorosilanes
url http://hdl.handle.net/11073/21332