Analysis of Sawdust by X-ray Photoelectron Spectroscopy

Determining the chemical structure and composition of biomass fuels using x-ray photoelectron spectroscopy (XPS) can provide fundamental knowledge of their structures that is useful in understanding and predicting their combustion behavior. Sawdust is an example of a forest product residue (byproduc...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Jiang, Guilin (author)
مؤلفون آخرون: Husseini, Ghaleb (author), Baxter, Larry L. (author), Linford, Matthew R. (author)
التنسيق: article
منشور في: 2005
الموضوعات:
الوصول للمادة أونلاين:http://hdl.handle.net/11073/21340
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الوصف
الملخص:Determining the chemical structure and composition of biomass fuels using x-ray photoelectron spectroscopy (XPS) can provide fundamental knowledge of their structures that is useful in understanding and predicting their combustion behavior. Sawdust is an example of a forest product residue (byproduct of paper and lumber production) of potential interest for biomass combustion. The XPS spectra of sawdust provide both its elemental composition and indications of its bonding. Traditional fuel analyses of this fuel are also provided. These include: ultimate analysis — the elemental composition of the overall fuel (C, H, N, S, and O); chlorine analysis — reported here as part of the ultimate analysis but formally a separate procedure; proximate analysis — the proximate composition of the fuel (moisture, fixed carbon, volatiles, and ash); heating value — the specific heat of combustion; ash chemistry analysis — an elemental analysis of the ash content, expressed as oxides (which does not imply that they occur as oxides in the fuel). These data are summarized with the XPS spectra.