Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural

The CuO-supported MCM-41 catalysts were prepared using a simple incipient wet impregnation method. The catalysts were investigated for hydrogenation of furfural to furfuryl alcohol synthesis. Among all the catalysts, the 2.5% CuO/MCM-41 catalyst shows the best catalytic performance with 92.5% conver...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Leela Prasad, Yandrati (author)
مؤلفون آخرون: Sekhar Kaladi, Swamy (author), Gundeboyina, Raveendra (author), Pothu, Ramakrishna (author), Moli, Vijaya (author), Venkateswara Rao, B. (author), Boddula, Rajender (author), Devulapalli, Rammohanrao (author), Mitta, Harisekhar (author)
التنسيق: article
منشور في: 2024
الموضوعات:
الوصول للمادة أونلاين:http://dx.doi.org/10.1016/j.catcom.2024.106898
https://www.sciencedirect.com/science/article/pii/S156673672400058X
http://hdl.handle.net/10576/65064
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الوصف
الملخص:The CuO-supported MCM-41 catalysts were prepared using a simple incipient wet impregnation method. The catalysts were investigated for hydrogenation of furfural to furfuryl alcohol synthesis. Among all the catalysts, the 2.5% CuO/MCM-41 catalyst shows the best catalytic performance with 92.5% conversion and 89% selectivity of furfuryl alcohol at 210 °C. The catalyst also demonstrated a high turnover frequency (TOF) of 154.4 h−1. The 2.5% CuO/MCM-41 catalyst remained stable for up to 20 h during the time on stream.