Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural
The CuO-supported MCM-41 catalysts were prepared using a simple incipient wet impregnation method. The catalysts were investigated for hydrogenation of furfural to furfuryl alcohol synthesis. Among all the catalysts, the 2.5% CuO/MCM-41 catalyst shows the best catalytic performance with 92.5% conver...
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2024
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| Online Access: | http://dx.doi.org/10.1016/j.catcom.2024.106898 https://www.sciencedirect.com/science/article/pii/S156673672400058X http://hdl.handle.net/10576/65064 |
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| _version_ | 1857415086718582784 |
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| author | Leela Prasad, Yandrati |
| author2 | Sekhar Kaladi, Swamy Gundeboyina, Raveendra Pothu, Ramakrishna Moli, Vijaya Venkateswara Rao, B. Boddula, Rajender Devulapalli, Rammohanrao Mitta, Harisekhar |
| author2_role | author author author author author author author author |
| author_facet | Leela Prasad, Yandrati Sekhar Kaladi, Swamy Gundeboyina, Raveendra Pothu, Ramakrishna Moli, Vijaya Venkateswara Rao, B. Boddula, Rajender Devulapalli, Rammohanrao Mitta, Harisekhar |
| author_role | author |
| dc.creator.none.fl_str_mv | Leela Prasad, Yandrati Sekhar Kaladi, Swamy Gundeboyina, Raveendra Pothu, Ramakrishna Moli, Vijaya Venkateswara Rao, B. Boddula, Rajender Devulapalli, Rammohanrao Mitta, Harisekhar |
| dc.date.none.fl_str_mv | 2024-02-29 2025-05-20T08:06:34Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://dx.doi.org/10.1016/j.catcom.2024.106898 15667367 https://www.sciencedirect.com/science/article/pii/S156673672400058X http://hdl.handle.net/10576/65064 187 |
| dc.language.none.fl_str_mv | en |
| dc.publisher.none.fl_str_mv | Elsevier |
| dc.rights.none.fl_str_mv | http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Hydrogenation Furfural Furfuryl alcohol CuO MCM-41 Sustainability energy & fuels Green chemistry |
| dc.title.none.fl_str_mv | Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural |
| dc.type.none.fl_str_mv | Article info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | The CuO-supported MCM-41 catalysts were prepared using a simple incipient wet impregnation method. The catalysts were investigated for hydrogenation of furfural to furfuryl alcohol synthesis. Among all the catalysts, the 2.5% CuO/MCM-41 catalyst shows the best catalytic performance with 92.5% conversion and 89% selectivity of furfuryl alcohol at 210 °C. The catalyst also demonstrated a high turnover frequency (TOF) of 154.4 h−1. The 2.5% CuO/MCM-41 catalyst remained stable for up to 20 h during the time on stream. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | qu_2ad9b995a67f181374e278e716853114 |
| identifier_str_mv | 15667367 187 |
| language_invalid_str_mv | en |
| network_acronym_str | qu |
| network_name_str | Qatar University repository |
| oai_identifier_str | oai:qspace.qu.edu.qa:10576/65064 |
| publishDate | 2024 |
| publisher.none.fl_str_mv | Elsevier |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| spelling | Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfuralLeela Prasad, YandratiSekhar Kaladi, SwamyGundeboyina, RaveendraPothu, RamakrishnaMoli, VijayaVenkateswara Rao, B.Boddula, RajenderDevulapalli, RammohanraoMitta, HarisekharHydrogenationFurfuralFurfuryl alcoholCuOMCM-41Sustainability energy & fuelsGreen chemistryThe CuO-supported MCM-41 catalysts were prepared using a simple incipient wet impregnation method. The catalysts were investigated for hydrogenation of furfural to furfuryl alcohol synthesis. Among all the catalysts, the 2.5% CuO/MCM-41 catalyst shows the best catalytic performance with 92.5% conversion and 89% selectivity of furfuryl alcohol at 210 °C. The catalyst also demonstrated a high turnover frequency (TOF) of 154.4 h−1. The 2.5% CuO/MCM-41 catalyst remained stable for up to 20 h during the time on stream.Elsevier2025-05-20T08:06:34Z2024-02-29Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://dx.doi.org/10.1016/j.catcom.2024.10689815667367https://www.sciencedirect.com/science/article/pii/S156673672400058Xhttp://hdl.handle.net/10576/65064187enhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:qspace.qu.edu.qa:10576/650642025-05-20T19:08:31Z |
| spellingShingle | Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural Leela Prasad, Yandrati Hydrogenation Furfural Furfuryl alcohol CuO MCM-41 Sustainability energy & fuels Green chemistry |
| status_str | publishedVersion |
| title | Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural |
| title_full | Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural |
| title_fullStr | Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural |
| title_full_unstemmed | Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural |
| title_short | Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural |
| title_sort | Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural |
| topic | Hydrogenation Furfural Furfuryl alcohol CuO MCM-41 Sustainability energy & fuels Green chemistry |
| url | http://dx.doi.org/10.1016/j.catcom.2024.106898 https://www.sciencedirect.com/science/article/pii/S156673672400058X http://hdl.handle.net/10576/65064 |