Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts
The extenuation of CO2 emissions using electrochemical CO2 reduction (ECR) is a promising approach. Electrochemical routes offer a number of benefits, including customizable layout, precise product modification, mild operational temperatures, and the ability to combine CO2 reduction with the product...
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| مؤلفون آخرون: | , , |
| التنسيق: | article |
| منشور في: |
2025
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| الموضوعات: | |
| الوصول للمادة أونلاين: | http://dx.doi.org/10.1016/j.ijhydene.2025.02.315 https://www.sciencedirect.com/science/article/pii/S0360319925008936 http://hdl.handle.net/10576/66675 |
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| _version_ | 1857415083734335488 |
|---|---|
| author | Saad, Mohammed A.H.S. |
| author2 | Al-Marri, Mohammed J. Kumar, Anand Yadav, V.S.K. |
| author2_role | author author author |
| author_facet | Saad, Mohammed A.H.S. Al-Marri, Mohammed J. Kumar, Anand Yadav, V.S.K. |
| author_role | author |
| dc.creator.none.fl_str_mv | Saad, Mohammed A.H.S. Al-Marri, Mohammed J. Kumar, Anand Yadav, V.S.K. |
| dc.date.none.fl_str_mv | 2025-07-30T10:39:14Z 2025-02-26 |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://dx.doi.org/10.1016/j.ijhydene.2025.02.315 Yadav, V. S. K., Saad, M. A., Al-Marri, M. J., & Kumar, A. (2025). Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts. International Journal of Hydrogen Energy. 0360-3199 https://www.sciencedirect.com/science/article/pii/S0360319925008936 http://hdl.handle.net/10576/66675 1142-1151 136 1879-3487 |
| dc.language.none.fl_str_mv | en |
| dc.publisher.none.fl_str_mv | Elsevier |
| dc.rights.none.fl_str_mv | http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Quartz crystal microbalance (QCM) CO2 reduction Sn Frequency Mass |
| dc.title.none.fl_str_mv | Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts |
| dc.type.none.fl_str_mv | Article info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | The extenuation of CO2 emissions using electrochemical CO2 reduction (ECR) is a promising approach. Electrochemical routes offer a number of benefits, including customizable layout, precise product modification, mild operational temperatures, and the ability to combine CO2 reduction with the production of renewable electricity. Nevertheless, the essential technique for reprocessing CO2 as a renewable resource is electrochemical CO2 reduction, yet CO2 adsorption/reduction on catalyst surfaces is challenging. To address these concerns, Mn3O4 and Sn were produced in this work at room temperature via an electrodeposition technique, which was combined with a quartz crystal microbalance (QCM) sensor suitable for room-temperature monitoring of ECR. QCM is a compelling technique for closely inspecting the responses of CO2 reduction in real time under various applied conditions. QCM was used for the first time to study the effects of Sn electrocatalysts for ECR research, and revealed the CO2 adsorption/reduction capabilities of diverse Sn catalysts. A broad investigation showed the CO2 reduction detecting ability of Sn coated QCM sensors at room temperature. The final results revealed that Sn catalysts' capacity to reduce CO2 was evident both with and without CO2 present in the solution of sodium bicarbonate electrolyte. For all the appropriate conditions, the effect of CO2 saturated electrolyte solution on the frequency and mass change with time along with applied potential were discussed in detail. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | qu_47e0a61332c3aa4838abb95dac7fdea6 |
| identifier_str_mv | Yadav, V. S. K., Saad, M. A., Al-Marri, M. J., & Kumar, A. (2025). Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts. International Journal of Hydrogen Energy. 0360-3199 1142-1151 136 1879-3487 |
| language_invalid_str_mv | en |
| network_acronym_str | qu |
| network_name_str | Qatar University repository |
| oai_identifier_str | oai:qspace.qu.edu.qa:10576/66675 |
| publishDate | 2025 |
| publisher.none.fl_str_mv | Elsevier |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | http://creativecommons.org/licenses/by/4.0/ |
| spelling | Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalystsSaad, Mohammed A.H.S.Al-Marri, Mohammed J.Kumar, AnandYadav, V.S.K.Quartz crystal microbalance (QCM)CO2 reductionSnFrequencyMassThe extenuation of CO2 emissions using electrochemical CO2 reduction (ECR) is a promising approach. Electrochemical routes offer a number of benefits, including customizable layout, precise product modification, mild operational temperatures, and the ability to combine CO2 reduction with the production of renewable electricity. Nevertheless, the essential technique for reprocessing CO2 as a renewable resource is electrochemical CO2 reduction, yet CO2 adsorption/reduction on catalyst surfaces is challenging. To address these concerns, Mn3O4 and Sn were produced in this work at room temperature via an electrodeposition technique, which was combined with a quartz crystal microbalance (QCM) sensor suitable for room-temperature monitoring of ECR. QCM is a compelling technique for closely inspecting the responses of CO2 reduction in real time under various applied conditions. QCM was used for the first time to study the effects of Sn electrocatalysts for ECR research, and revealed the CO2 adsorption/reduction capabilities of diverse Sn catalysts. A broad investigation showed the CO2 reduction detecting ability of Sn coated QCM sensors at room temperature. The final results revealed that Sn catalysts' capacity to reduce CO2 was evident both with and without CO2 present in the solution of sodium bicarbonate electrolyte. For all the appropriate conditions, the effect of CO2 saturated electrolyte solution on the frequency and mass change with time along with applied potential were discussed in detail.Elsevier2025-07-30T10:39:14Z2025-02-26Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://dx.doi.org/10.1016/j.ijhydene.2025.02.315Yadav, V. S. K., Saad, M. A., Al-Marri, M. J., & Kumar, A. (2025). Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts. International Journal of Hydrogen Energy.0360-3199https://www.sciencedirect.com/science/article/pii/S0360319925008936http://hdl.handle.net/10576/666751142-11511361879-3487enhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:qspace.qu.edu.qa:10576/666752025-07-30T19:05:21Z |
| spellingShingle | Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts Saad, Mohammed A.H.S. Quartz crystal microbalance (QCM) CO2 reduction Sn Frequency Mass |
| status_str | publishedVersion |
| title | Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts |
| title_full | Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts |
| title_fullStr | Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts |
| title_full_unstemmed | Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts |
| title_short | Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts |
| title_sort | Quartz crystal microbalance (QCM) study of electrochemical CO2 reduction on Sn electrocatalysts |
| topic | Quartz crystal microbalance (QCM) CO2 reduction Sn Frequency Mass |
| url | http://dx.doi.org/10.1016/j.ijhydene.2025.02.315 https://www.sciencedirect.com/science/article/pii/S0360319925008936 http://hdl.handle.net/10576/66675 |