Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse

This study presents an experimental investigation and a parametric analysis of the applicability of agricultural fertigation and power generation using a reverse electrodialysis-forward osmosis (RED-FO) hybrid system, with a water stream discharged from a fertilizer-producing plant. The results of t...

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محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Tasneem, Elmakki (author)
مؤلفون آخرون: Zavahir, Sifani (author), Gulied, Mona (author), Qiblawey, Hazim (author), Hammadi, Bassim (author), Khraisheh, Majeda (author), Shon, Ho Kyong (author), Park, Hyunwoong (author), Han, Dong Suk (author)
التنسيق: article
منشور في: 2023
الموضوعات:
الوصول للمادة أونلاين:http://dx.doi.org/10.1016/j.desal.2023.116374
https://www.sciencedirect.com/science/article/pii/S0011916423000061
http://hdl.handle.net/10576/41595
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_version_ 1857415087420080128
author Tasneem, Elmakki
author2 Zavahir, Sifani
Gulied, Mona
Qiblawey, Hazim
Hammadi, Bassim
Khraisheh, Majeda
Shon, Ho Kyong
Park, Hyunwoong
Han, Dong Suk
author2_role author
author
author
author
author
author
author
author
author_facet Tasneem, Elmakki
Zavahir, Sifani
Gulied, Mona
Qiblawey, Hazim
Hammadi, Bassim
Khraisheh, Majeda
Shon, Ho Kyong
Park, Hyunwoong
Han, Dong Suk
author_role author
dc.creator.none.fl_str_mv Tasneem, Elmakki
Zavahir, Sifani
Gulied, Mona
Qiblawey, Hazim
Hammadi, Bassim
Khraisheh, Majeda
Shon, Ho Kyong
Park, Hyunwoong
Han, Dong Suk
dc.date.none.fl_str_mv 2023-04-03T07:55:55Z
2023-01-14
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv http://dx.doi.org/10.1016/j.desal.2023.116374
Elmakki, T., Zavahir, S., Gulied, M., Qiblawey, H., Hammadi, B., Khraisheh, M., ... & Han, D. S. (2023). Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse. Desalination, 550, 116374.
0011-9164
https://www.sciencedirect.com/science/article/pii/S0011916423000061
http://hdl.handle.net/10576/41595
550
1873-4464
dc.language.none.fl_str_mv en
dc.publisher.none.fl_str_mv Elsevier
dc.rights.none.fl_str_mv http://creativecommons.org/licenses/by/4.0/
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Reverse electrodialysis (RED)
Forward osmosis (FO)
Blue energy
Water reuse
Agricultural fertigation
Fertilizer-producing industry
Reverse osmosis (RO) brine
dc.title.none.fl_str_mv Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse
dc.type.none.fl_str_mv Article
info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/article
description This study presents an experimental investigation and a parametric analysis of the applicability of agricultural fertigation and power generation using a reverse electrodialysis-forward osmosis (RED-FO) hybrid system, with a water stream discharged from a fertilizer-producing plant. The results of this study demonstrated the possibility of achieving high salinity power generation from the RED system utilizing high-salinity brine and low-salinity ammonia solution that simulates reverse osmosis (RO) brine and wastewater streams released by the fertilizer-producing industry. The feasibility of stream dilution for fertigation application is demonstrated when the resulting moderately saline RED effluent is introduced into the FO process as a draw solution. The effect of external load addition, flow velocities variation, and concentration changes of the working solutions on the overall stack internal resistance and, thereby, RED performance was evaluated. As such, the lowest internal resistance converged to a threshold value of 4.03 Ω, giving the highest gross power density of 2.17 W/m2 when a flow velocity of 1.18 cm/s, 10 Ω external load, and 0.015 M (NH4)2SO4/1 M NaCl solution pair were utilized. In addition, the effect of the number of ion exchange membrane pairs and wastewater stream recycling was studied and optimized to amplify the osmotically generated power. As a result, the most consistent power generation was achieved when using 20 pairs of membrane cells in a single-pass flow mode operation. The applicability of the RED effluent to a subsequent FO system as a draw solution (DS) was investigated, showing a dilution rate (17 %) and a conductivity (1–2 mS/cm of DS) suitable for agricultural fertigation applications.
eu_rights_str_mv openAccess
format article
id qu_6de7ff2cc89aa5665b653960557174c5
identifier_str_mv Elmakki, T., Zavahir, S., Gulied, M., Qiblawey, H., Hammadi, B., Khraisheh, M., ... & Han, D. S. (2023). Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse. Desalination, 550, 116374.
0011-9164
550
1873-4464
language_invalid_str_mv en
network_acronym_str qu
network_name_str Qatar University repository
oai_identifier_str oai:qspace.qu.edu.qa:10576/41595
publishDate 2023
publisher.none.fl_str_mv Elsevier
repository.mail.fl_str_mv
repository.name.fl_str_mv
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rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
spelling Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuseTasneem, ElmakkiZavahir, SifaniGulied, MonaQiblawey, HazimHammadi, BassimKhraisheh, MajedaShon, Ho KyongPark, HyunwoongHan, Dong SukReverse electrodialysis (RED)Forward osmosis (FO)Blue energyWater reuseAgricultural fertigationFertilizer-producing industryReverse osmosis (RO) brineThis study presents an experimental investigation and a parametric analysis of the applicability of agricultural fertigation and power generation using a reverse electrodialysis-forward osmosis (RED-FO) hybrid system, with a water stream discharged from a fertilizer-producing plant. The results of this study demonstrated the possibility of achieving high salinity power generation from the RED system utilizing high-salinity brine and low-salinity ammonia solution that simulates reverse osmosis (RO) brine and wastewater streams released by the fertilizer-producing industry. The feasibility of stream dilution for fertigation application is demonstrated when the resulting moderately saline RED effluent is introduced into the FO process as a draw solution. The effect of external load addition, flow velocities variation, and concentration changes of the working solutions on the overall stack internal resistance and, thereby, RED performance was evaluated. As such, the lowest internal resistance converged to a threshold value of 4.03 Ω, giving the highest gross power density of 2.17 W/m2 when a flow velocity of 1.18 cm/s, 10 Ω external load, and 0.015 M (NH4)2SO4/1 M NaCl solution pair were utilized. In addition, the effect of the number of ion exchange membrane pairs and wastewater stream recycling was studied and optimized to amplify the osmotically generated power. As a result, the most consistent power generation was achieved when using 20 pairs of membrane cells in a single-pass flow mode operation. The applicability of the RED effluent to a subsequent FO system as a draw solution (DS) was investigated, showing a dilution rate (17 %) and a conductivity (1–2 mS/cm of DS) suitable for agricultural fertigation applications.This publication was funded by the Qatar National Research Fund (QNRF) grant (# NPRP13S-0202-200228 ), Qatar Fertilizer Company (QAFCO) grant ( QUEX-CAM-QAFCO-20/21-1 ), the National Research Foundation of Korea ( 2018R1A6A1A03024962 and 2019R1A2C2002602 ), and the Ministry of Trade, Industry, and Energy (MOTIE), Korea ( 2021-20015633 ).Elsevier2023-04-03T07:55:55Z2023-01-14Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://dx.doi.org/10.1016/j.desal.2023.116374Elmakki, T., Zavahir, S., Gulied, M., Qiblawey, H., Hammadi, B., Khraisheh, M., ... & Han, D. S. (2023). Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse. Desalination, 550, 116374.0011-9164https://www.sciencedirect.com/science/article/pii/S0011916423000061http://hdl.handle.net/10576/415955501873-4464enhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:qspace.qu.edu.qa:10576/415952025-05-25T08:50:08Z
spellingShingle Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse
Tasneem, Elmakki
Reverse electrodialysis (RED)
Forward osmosis (FO)
Blue energy
Water reuse
Agricultural fertigation
Fertilizer-producing industry
Reverse osmosis (RO) brine
status_str publishedVersion
title Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse
title_full Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse
title_fullStr Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse
title_full_unstemmed Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse
title_short Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse
title_sort Potential application of hybrid reverse electrodialysis (RED)-forward osmosis (FO) system to fertilizer-producing industrial plant for efficient water reuse
topic Reverse electrodialysis (RED)
Forward osmosis (FO)
Blue energy
Water reuse
Agricultural fertigation
Fertilizer-producing industry
Reverse osmosis (RO) brine
url http://dx.doi.org/10.1016/j.desal.2023.116374
https://www.sciencedirect.com/science/article/pii/S0011916423000061
http://hdl.handle.net/10576/41595