Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review
The research towards the development of alternative fuel generation technologies has been triggered by Climate change, global warming, and the ongoing depletion of fossil fuels. The hydrogenation of carbon dioxide (CO2) into methanol, dimethyl ether, carbon monoxide, and value-added products appears...
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| مؤلفون آخرون: | , , , |
| التنسيق: | article |
| منشور في: |
2023
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| الموضوعات: | |
| الوصول للمادة أونلاين: | http://dx.doi.org/10.1016/j.eti.2023.103217 https://www.sciencedirect.com/science/article/pii/S2352186423002134 http://hdl.handle.net/10576/65689 |
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| _version_ | 1857415083744821248 |
|---|---|
| author | Tawalbeh, Muhammad |
| author2 | Javed, Rana Muhammad Nauman Al-Othman, Amani Almomani, Fares Ajith, Saniha |
| author2_role | author author author author |
| author_facet | Tawalbeh, Muhammad Javed, Rana Muhammad Nauman Al-Othman, Amani Almomani, Fares Ajith, Saniha |
| author_role | author |
| dc.creator.none.fl_str_mv | Tawalbeh, Muhammad Javed, Rana Muhammad Nauman Al-Othman, Amani Almomani, Fares Ajith, Saniha |
| dc.date.none.fl_str_mv | 2023-08-31 2025-06-23T08:42:39Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://dx.doi.org/10.1016/j.eti.2023.103217 Tawalbeh, M., Javed, R. M. N., Al-Othman, A., Almomani, F., & Ajith, S. (2023). Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review. Environmental Technology & Innovation, 31, 103217. 23521864 https://www.sciencedirect.com/science/article/pii/S2352186423002134 http://hdl.handle.net/10576/65689 31 |
| dc.language.none.fl_str_mv | en |
| dc.publisher.none.fl_str_mv | Elsevier |
| dc.rights.none.fl_str_mv | http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Added value products Nano-catalysis Reaction pathways Yield Selectivity Enhanced conversion process |
| dc.title.none.fl_str_mv | Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review |
| dc.type.none.fl_str_mv | Article info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | The research towards the development of alternative fuel generation technologies has been triggered by Climate change, global warming, and the ongoing depletion of fossil fuels. The hydrogenation of carbon dioxide (CO2) into methanol, dimethyl ether, carbon monoxide, and value-added products appears to be a promising path to mitigate CO2 emissions. The role of noble metal catalysts (Pt, Pd, Rh, Au, etc.) in CO2 conversion into useful products has been addressed in this work. The literature reported improved catalytic performance of the reverse water-gas shift (RWGS) reaction, and several studies were examined for the optimal performance in CO2 hydrogenation processes. The focus was on the preparation techniques, supporting materials, noble metals loading, and reactions mechanism. This paper shows the most notable results in the application of noble metals and demonstrates an enhanced CO2 conversion of 80% and CO selectivity of >99%. Furthermore, this review demonstrated the promising role of Au-based catalysts in improving the kinetics of the CO2 hydrogenation reaction with 80% methanol selectivity when nano-sized zinc oxide particles were involved. Recently, CO2 hydrogenation with photothermal catalysis resulted in a high methane yield and selectivity of 100%. Notable research paths were directed toward the investigation of Au and Pd-based catalysts and exploited them to produce formats compounds with promising conversion. Furthermore, the synthesis of heterogeneous oxide-zeolite (OX-ZEO) bi-functional catalysts for improved CO2 hydrogenation can be explored in reactors powered by renewable energy sources. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | qu_830c16ad8d527e5b6940864e567c6b5b |
| identifier_str_mv | Tawalbeh, M., Javed, R. M. N., Al-Othman, A., Almomani, F., & Ajith, S. (2023). Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review. Environmental Technology & Innovation, 31, 103217. 23521864 31 |
| language_invalid_str_mv | en |
| network_acronym_str | qu |
| network_name_str | Qatar University repository |
| oai_identifier_str | oai:qspace.qu.edu.qa:10576/65689 |
| publishDate | 2023 |
| publisher.none.fl_str_mv | Elsevier |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | http://creativecommons.org/licenses/by/4.0/ |
| spelling | Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive reviewTawalbeh, MuhammadJaved, Rana Muhammad NaumanAl-Othman, AmaniAlmomani, FaresAjith, SanihaAdded value productsNano-catalysisReaction pathwaysYieldSelectivityEnhanced conversion processThe research towards the development of alternative fuel generation technologies has been triggered by Climate change, global warming, and the ongoing depletion of fossil fuels. The hydrogenation of carbon dioxide (CO2) into methanol, dimethyl ether, carbon monoxide, and value-added products appears to be a promising path to mitigate CO2 emissions. The role of noble metal catalysts (Pt, Pd, Rh, Au, etc.) in CO2 conversion into useful products has been addressed in this work. The literature reported improved catalytic performance of the reverse water-gas shift (RWGS) reaction, and several studies were examined for the optimal performance in CO2 hydrogenation processes. The focus was on the preparation techniques, supporting materials, noble metals loading, and reactions mechanism. This paper shows the most notable results in the application of noble metals and demonstrates an enhanced CO2 conversion of 80% and CO selectivity of >99%. Furthermore, this review demonstrated the promising role of Au-based catalysts in improving the kinetics of the CO2 hydrogenation reaction with 80% methanol selectivity when nano-sized zinc oxide particles were involved. Recently, CO2 hydrogenation with photothermal catalysis resulted in a high methane yield and selectivity of 100%. Notable research paths were directed toward the investigation of Au and Pd-based catalysts and exploited them to produce formats compounds with promising conversion. Furthermore, the synthesis of heterogeneous oxide-zeolite (OX-ZEO) bi-functional catalysts for improved CO2 hydrogenation can be explored in reactors powered by renewable energy sources.The authors would like to thank the University of Sharjah, United Arab Emirates for financial support via the competitive research grant project number: 22020406230. The authors would like to acknowledge the open access funding provided by the Qatar National Library .Elsevier2025-06-23T08:42:39Z2023-08-31Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://dx.doi.org/10.1016/j.eti.2023.103217Tawalbeh, M., Javed, R. M. N., Al-Othman, A., Almomani, F., & Ajith, S. (2023). Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review. Environmental Technology & Innovation, 31, 103217.23521864https://www.sciencedirect.com/science/article/pii/S2352186423002134http://hdl.handle.net/10576/6568931enhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:qspace.qu.edu.qa:10576/656892025-06-23T19:07:25Z |
| spellingShingle | Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review Tawalbeh, Muhammad Added value products Nano-catalysis Reaction pathways Yield Selectivity Enhanced conversion process |
| status_str | publishedVersion |
| title | Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review |
| title_full | Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review |
| title_fullStr | Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review |
| title_full_unstemmed | Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review |
| title_short | Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review |
| title_sort | Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review |
| topic | Added value products Nano-catalysis Reaction pathways Yield Selectivity Enhanced conversion process |
| url | http://dx.doi.org/10.1016/j.eti.2023.103217 https://www.sciencedirect.com/science/article/pii/S2352186423002134 http://hdl.handle.net/10576/65689 |