Ion-imprinted membranes for lithium recovery: A review
This review critically examines the effectiveness of ion-imprinted membranes (IIMs) in selectively recovering lithium (Li) from challenging sources such as seawater and brine. These membranes feature customized binding sites that specifically target Li ions, enabling selective separation from other...
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2024
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| Online Access: | http://dx.doi.org/10.1016/j.chemosphere.2024.141674 https://www.sciencedirect.com/science/article/pii/S0045653524005678 http://hdl.handle.net/10576/52999 |
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| _version_ | 1857415086045396992 |
|---|---|
| author | Sifani, Zavahir |
| author2 | Riyaz, Najamus Sahar Elmakki, Tasneem Tariq, Haseeb Ahmad, Zubair Chen, Yuan Park, Hyunwoong Ho, Yeek-Chia Shon, Ho Kyong Han, Dong Suk |
| author2_role | author author author author author author author author author |
| author_facet | Sifani, Zavahir Riyaz, Najamus Sahar Elmakki, Tasneem Tariq, Haseeb Ahmad, Zubair Chen, Yuan Park, Hyunwoong Ho, Yeek-Chia Shon, Ho Kyong Han, Dong Suk |
| author_role | author |
| dc.creator.none.fl_str_mv | Sifani, Zavahir Riyaz, Najamus Sahar Elmakki, Tasneem Tariq, Haseeb Ahmad, Zubair Chen, Yuan Park, Hyunwoong Ho, Yeek-Chia Shon, Ho Kyong Han, Dong Suk |
| dc.date.none.fl_str_mv | 2024-03-13T07:51:42Z 2024-04-30 |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://dx.doi.org/10.1016/j.chemosphere.2024.141674 00456535 https://www.sciencedirect.com/science/article/pii/S0045653524005678 http://hdl.handle.net/10576/52999 354 1879-1298 |
| dc.language.none.fl_str_mv | en |
| dc.publisher.none.fl_str_mv | Elsevier |
| dc.rights.none.fl_str_mv | http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Lithium Seawater Brine Recovery Ion-imprinted membrane (IIM) |
| dc.title.none.fl_str_mv | Ion-imprinted membranes for lithium recovery: A review |
| dc.type.none.fl_str_mv | Article info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | This review critically examines the effectiveness of ion-imprinted membranes (IIMs) in selectively recovering lithium (Li) from challenging sources such as seawater and brine. These membranes feature customized binding sites that specifically target Li ions, enabling selective separation from other ions, thanks to cavities shaped with crown ether or calixarene for improved selectivity. The review thoroughly investigates the application of IIMs in Li extraction, covering extensive sections on 12-crown-4 ether (a fundamental crown ether for Li), its modifications, calixarenes, and other materials for creating imprinting sites. It evaluates these systems against several criteria, including the source solution's complexity, Li+ concentration, operational pH, selectivity, and membrane's ability for regeneration and repeated use. This evaluation places IIMs as a leading-edge technology for Li extraction, surpassing traditional methods like ion-sieves, particularly in high Mg2+/Li+ ratio brines. It also highlights the developmental challenges of IIMs, focusing on optimizing adsorption, maintaining selectivity across varied ionic solutions, and enhancing permselectivity. The review reveals that while the bulk of research is still exploratory, only a limited portion has progressed to detailed lab verification, indicating that the application of IIMs in Li+ recovery is still at an embryonic stage, with no instances of pilot-scale trials reported. This thorough review elucidates the potential of IIMs in Li recovery, cataloging advancements, pinpointing challenges, and suggesting directions for forthcoming research endeavors. This informative synthesis serves as a valuable resource for both the scientific community and industry professionals navigating this evolving field. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | qu_8a5aecfab081a7c8d5eedf6732ba3cb4 |
| identifier_str_mv | 00456535 354 1879-1298 |
| language_invalid_str_mv | en |
| network_acronym_str | qu |
| network_name_str | Qatar University repository |
| oai_identifier_str | oai:qspace.qu.edu.qa:10576/52999 |
| publishDate | 2024 |
| publisher.none.fl_str_mv | Elsevier |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | http://creativecommons.org/licenses/by/4.0/ |
| spelling | Ion-imprinted membranes for lithium recovery: A reviewSifani, ZavahirRiyaz, Najamus SaharElmakki, TasneemTariq, HaseebAhmad, ZubairChen, YuanPark, HyunwoongHo, Yeek-ChiaShon, Ho KyongHan, Dong SukLithiumSeawaterBrineRecoveryIon-imprinted membrane (IIM)This review critically examines the effectiveness of ion-imprinted membranes (IIMs) in selectively recovering lithium (Li) from challenging sources such as seawater and brine. These membranes feature customized binding sites that specifically target Li ions, enabling selective separation from other ions, thanks to cavities shaped with crown ether or calixarene for improved selectivity. The review thoroughly investigates the application of IIMs in Li extraction, covering extensive sections on 12-crown-4 ether (a fundamental crown ether for Li), its modifications, calixarenes, and other materials for creating imprinting sites. It evaluates these systems against several criteria, including the source solution's complexity, Li+ concentration, operational pH, selectivity, and membrane's ability for regeneration and repeated use. This evaluation places IIMs as a leading-edge technology for Li extraction, surpassing traditional methods like ion-sieves, particularly in high Mg2+/Li+ ratio brines. It also highlights the developmental challenges of IIMs, focusing on optimizing adsorption, maintaining selectivity across varied ionic solutions, and enhancing permselectivity. The review reveals that while the bulk of research is still exploratory, only a limited portion has progressed to detailed lab verification, indicating that the application of IIMs in Li+ recovery is still at an embryonic stage, with no instances of pilot-scale trials reported. This thorough review elucidates the potential of IIMs in Li recovery, cataloging advancements, pinpointing challenges, and suggesting directions for forthcoming research endeavors. This informative synthesis serves as a valuable resource for both the scientific community and industry professionals navigating this evolving field.This study is made possible by Qatar National Research Fund (QNRF) under National Priorities Research Program (NPRP) grant (#NPRP12S-0227-190166). Open Access funding is provided by the Qatar National Library (QNL). H.P. is grateful to the National Research Foundation of Korea for financial support (RS-2023-00254645).Elsevier2024-03-13T07:51:42Z2024-04-30Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://dx.doi.org/10.1016/j.chemosphere.2024.14167400456535https://www.sciencedirect.com/science/article/pii/S0045653524005678http://hdl.handle.net/10576/529993541879-1298enhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:qspace.qu.edu.qa:10576/529992024-07-23T10:58:39Z |
| spellingShingle | Ion-imprinted membranes for lithium recovery: A review Sifani, Zavahir Lithium Seawater Brine Recovery Ion-imprinted membrane (IIM) |
| status_str | publishedVersion |
| title | Ion-imprinted membranes for lithium recovery: A review |
| title_full | Ion-imprinted membranes for lithium recovery: A review |
| title_fullStr | Ion-imprinted membranes for lithium recovery: A review |
| title_full_unstemmed | Ion-imprinted membranes for lithium recovery: A review |
| title_short | Ion-imprinted membranes for lithium recovery: A review |
| title_sort | Ion-imprinted membranes for lithium recovery: A review |
| topic | Lithium Seawater Brine Recovery Ion-imprinted membrane (IIM) |
| url | http://dx.doi.org/10.1016/j.chemosphere.2024.141674 https://www.sciencedirect.com/science/article/pii/S0045653524005678 http://hdl.handle.net/10576/52999 |