Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction
The electrochemical reduction of carbon dioxide (eCO2RR) has become a very promising pathway that can be used in the transformation of CO2 to important chemical products and, thus, is one of the mitigations of climate change and will contribute toward sustainable chemical production. This review aim...
محفوظ في:
| المؤلف الرئيسي: | |
|---|---|
| مؤلفون آخرون: | , , , , , , , , |
| التنسيق: | article |
| منشور في: |
2025
|
| الموضوعات: | |
| الوصول للمادة أونلاين: | http://dx.doi.org/10.1016/j.jelechem.2025.119097 https://www.sciencedirect.com/science/article/pii/S1572665725001717 http://hdl.handle.net/10576/65938 |
| الوسوم: |
إضافة وسم
لا توجد وسوم, كن أول من يضع وسما على هذه التسجيلة!
|
| _version_ | 1857415083655692288 |
|---|---|
| author | Aymen S., Abu Hatab |
| author2 | Ahmad, Yahia H. Mady, Mohamed F. Hassan, Yasser Zkria, Abdelrahman Sinopoli, Alessandro Abdullah, Aboubakr M. Al-Qaradawi, Siham Y. Yoshitake, Tsuyoshi Khaled, Mazen |
| author2_role | author author author author author author author author author |
| author_facet | Aymen S., Abu Hatab Ahmad, Yahia H. Mady, Mohamed F. Hassan, Yasser Zkria, Abdelrahman Sinopoli, Alessandro Abdullah, Aboubakr M. Al-Qaradawi, Siham Y. Yoshitake, Tsuyoshi Khaled, Mazen |
| author_role | author |
| dc.creator.none.fl_str_mv | Aymen S., Abu Hatab Ahmad, Yahia H. Mady, Mohamed F. Hassan, Yasser Zkria, Abdelrahman Sinopoli, Alessandro Abdullah, Aboubakr M. Al-Qaradawi, Siham Y. Yoshitake, Tsuyoshi Khaled, Mazen |
| dc.date.none.fl_str_mv | 2025-07-03T05:13:59Z 2025-06-01 |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://dx.doi.org/10.1016/j.jelechem.2025.119097 Hatab, A. S. A., Ahmad, Y. H., Mady, M. F., Hassan, Y., Zkria, A., Sinopoli, A., ... & Khaled, M. (2025). Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction. Journal of Electroanalytical Chemistry, 119097. 15726657 https://www.sciencedirect.com/science/article/pii/S1572665725001717 http://hdl.handle.net/10576/65938 986 1873-2569 |
| dc.language.none.fl_str_mv | en |
| dc.publisher.none.fl_str_mv | Elsevier |
| dc.rights.none.fl_str_mv | http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Quantitative NMR CO2 utilization Electrocatalysis CO2 electroreduction Value-added multi‑carbon compounds |
| dc.title.none.fl_str_mv | Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction |
| dc.type.none.fl_str_mv | Article info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | The electrochemical reduction of carbon dioxide (eCO2RR) has become a very promising pathway that can be used in the transformation of CO2 to important chemical products and, thus, is one of the mitigations of climate change and will contribute toward sustainable chemical production. This review aims at presenting the importance of Nuclear Magnetic Resonance spectroscopy (NMR) to analyze and quantify the liquid-phase products obtained by eCO2RR. This provides a summary regarding the role that NMR plays in the process of reducing carbon dioxide. The following discusses the benefits: identification, complete elucidation, and follow-up on reactions involving CO2 electro-reduction. Pulse experiments corresponding to different methods for water signal suppression are considered separately, outlining some recent developments in the interference water signal reduction which is very crucial for the correct NMR data acquisition in aqueous electrolytes. Certain selected products are described, like carbon monoxide (CO)-associated liquids, formic acid, methanol, and formaldehyde as examples of the NMR precision for the characterization of important compounds. Further, the quantification of C2 products such as ethanol and acetate is discussed in order to illustrate how the technique can be applied in the elucidation of reaction mechanisms and optimization of catalyst performance. This review covers challenges, advanced methodologies, and emerging trends in order to underline the transformative role that NMR plays in advancing CO2 electrochemical reduction toward sustainable chemical synthesis. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | qu_bed6f2fa3409d39daf5297e043eac965 |
| identifier_str_mv | Hatab, A. S. A., Ahmad, Y. H., Mady, M. F., Hassan, Y., Zkria, A., Sinopoli, A., ... & Khaled, M. (2025). Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction. Journal of Electroanalytical Chemistry, 119097. 15726657 986 1873-2569 |
| language_invalid_str_mv | en |
| network_acronym_str | qu |
| network_name_str | Qatar University repository |
| oai_identifier_str | oai:qspace.qu.edu.qa:10576/65938 |
| publishDate | 2025 |
| publisher.none.fl_str_mv | Elsevier |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | http://creativecommons.org/licenses/by/4.0/ |
| spelling | Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reductionAymen S., Abu HatabAhmad, Yahia H.Mady, Mohamed F.Hassan, YasserZkria, AbdelrahmanSinopoli, AlessandroAbdullah, Aboubakr M.Al-Qaradawi, Siham Y.Yoshitake, TsuyoshiKhaled, MazenQuantitative NMRCO2 utilizationElectrocatalysisCO2 electroreductionValue-added multi‑carbon compoundsThe electrochemical reduction of carbon dioxide (eCO2RR) has become a very promising pathway that can be used in the transformation of CO2 to important chemical products and, thus, is one of the mitigations of climate change and will contribute toward sustainable chemical production. This review aims at presenting the importance of Nuclear Magnetic Resonance spectroscopy (NMR) to analyze and quantify the liquid-phase products obtained by eCO2RR. This provides a summary regarding the role that NMR plays in the process of reducing carbon dioxide. The following discusses the benefits: identification, complete elucidation, and follow-up on reactions involving CO2 electro-reduction. Pulse experiments corresponding to different methods for water signal suppression are considered separately, outlining some recent developments in the interference water signal reduction which is very crucial for the correct NMR data acquisition in aqueous electrolytes. Certain selected products are described, like carbon monoxide (CO)-associated liquids, formic acid, methanol, and formaldehyde as examples of the NMR precision for the characterization of important compounds. Further, the quantification of C2 products such as ethanol and acetate is discussed in order to illustrate how the technique can be applied in the elucidation of reaction mechanisms and optimization of catalyst performance. This review covers challenges, advanced methodologies, and emerging trends in order to underline the transformative role that NMR plays in advancing CO2 electrochemical reduction toward sustainable chemical synthesis.This work was made possible by the Qatar-Japan Research Collaboration Research Program, funded by Marubeni, under grant number M-QJRC-2023-312. The statements made herein are solely the responsibility of the authors. Open Access funding is provided by the Qatar National Library.Elsevier2025-07-03T05:13:59Z2025-06-01Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://dx.doi.org/10.1016/j.jelechem.2025.119097Hatab, A. S. A., Ahmad, Y. H., Mady, M. F., Hassan, Y., Zkria, A., Sinopoli, A., ... & Khaled, M. (2025). Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction. Journal of Electroanalytical Chemistry, 119097.15726657https://www.sciencedirect.com/science/article/pii/S1572665725001717http://hdl.handle.net/10576/659389861873-2569enhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:qspace.qu.edu.qa:10576/659382025-07-03T19:05:13Z |
| spellingShingle | Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction Aymen S., Abu Hatab Quantitative NMR CO2 utilization Electrocatalysis CO2 electroreduction Value-added multi‑carbon compounds |
| status_str | publishedVersion |
| title | Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction |
| title_full | Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction |
| title_fullStr | Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction |
| title_full_unstemmed | Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction |
| title_short | Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction |
| title_sort | Nuclear magnetic resonance spectroscopy: A comprehensive tool for analyzing liquid products in electrochemical CO2 reduction |
| topic | Quantitative NMR CO2 utilization Electrocatalysis CO2 electroreduction Value-added multi‑carbon compounds |
| url | http://dx.doi.org/10.1016/j.jelechem.2025.119097 https://www.sciencedirect.com/science/article/pii/S1572665725001717 http://hdl.handle.net/10576/65938 |