Crosslinked chitosan–montmorillonite composite and its magnetized counterpart for the removal of basic fuchsin from wastewater: Parametric optimization using Box-Behnken design
Treating wastewater polluted with organic dyestuffs is still a challenge. In that vein, facile synthesis of a structurally simple composite of chitosan with montmorillonite (CS-MMT) using glutaraldehyde as a crosslinker and the magnetized analogue (MAG@CS-MMT) was proposed as versatile adsorbents fo...
محفوظ في:
| المؤلف الرئيسي: | |
|---|---|
| مؤلفون آخرون: | |
| التنسيق: | article |
| منشور في: |
2024
|
| الموضوعات: | |
| الوصول للمادة أونلاين: | http://dx.doi.org/10.1016/j.ijbiomac.2024.130224 https://www.sciencedirect.com/science/article/pii/S0141813024010274 http://hdl.handle.net/10576/52777 |
| الوسوم: |
إضافة وسم
لا توجد وسوم, كن أول من يضع وسما على هذه التسجيلة!
|
| الملخص: | Treating wastewater polluted with organic dyestuffs is still a challenge. In that vein, facile synthesis of a structurally simple composite of chitosan with montmorillonite (CS-MMT) using glutaraldehyde as a crosslinker and the magnetized analogue (MAG@CS-MMT) was proposed as versatile adsorbents for the cationic dye, basic Fuchsin (FUS). Statistical modeling of the adsorption process was mediated using Box-Behnken (BB) design and by varying the composite dose, pH, [FUS], and contact time. Characterization of both composites showed an enhancement of surface features upon magnetization, substantiating a better FUS removal of the MAG@CS-MMT (%R = 98.43 %) compared to CS-MMT (%R = 68.02 %). The surface area analysis demonstrates that MAG@CS-MMT possesses a higher surface area, measuring 41.54 m2/g, and the surface analysis of the magnetized nanocomposite, conducted using FT-IR and Raman spectroscopies, proved the presence of FeO peaks. In the same context, adsorption of FUS onto MAG@CS-MMT fitted-well to the Langmuir isotherm model and the maximum adsorption capacities (qm) were 53.11 mg/g for CS-MMT and 88.34 mg/g for MAG@CS-MMT. Kinetics investigation shows that experimental data fitted well to the pseudo-second order (PSO) model. Regeneration study reveals that MAG@CS-MMT can be recovered effectively for repeated use with a high adsorption efficiency for FUS. |
|---|