Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene
The influence of adding waste wax, produced as a by-product of the low density polyethylene manufacturing process, on the thermal and mechanical properties of three types of polyethylene (PE), high-density polyethylene (HDPE), linear low-density polyethylene (LLDPE) and low-density polyethylene (LDP...
محفوظ في:
| المؤلف الرئيسي: | |
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| مؤلفون آخرون: | , , |
| التنسيق: | article |
| منشور في: |
2015
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| الموضوعات: | |
| الوصول للمادة أونلاين: | http://dx.doi.org/10.1016/j.arabjc.2014.01.006 http://www.sciencedirect.com/science/article/pii/S1878535214000094 http://hdl.handle.net/10576/4766 |
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| _version_ | 1857415087251259392 |
|---|---|
| author | AlMaadeed, M.A. |
| author2 | Labidi, Sami Krupa, Igor Ouederni, Mabrouk |
| author2_role | author author author |
| author_facet | AlMaadeed, M.A. Labidi, Sami Krupa, Igor Ouederni, Mabrouk |
| author_role | author |
| dc.creator.none.fl_str_mv | AlMaadeed, M.A. Labidi, Sami Krupa, Igor Ouederni, Mabrouk |
| dc.date.none.fl_str_mv | 2015-05 2016-09-25T09:39:52Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://dx.doi.org/10.1016/j.arabjc.2014.01.006 M.A. AlMaadeed, Sami Labidi, Igor Krupa, Mabrouk Ouederni, Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene, Arabian Journal of Chemistry, Volume 8, Issue 3, May 2015, Pages 388-399. 18785352 http://www.sciencedirect.com/science/article/pii/S1878535214000094 http://hdl.handle.net/10576/4766 388-399 3 8 |
| dc.language.none.fl_str_mv | en |
| dc.publisher.none.fl_str_mv | Elsevier B.V. |
| dc.rights.none.fl_str_mv | http://creativecommons.org/licenses/by-nc-nd/3.0/ info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Polyethylene Waste wax Mechanical properties Thermal properties |
| dc.title.none.fl_str_mv | Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene |
| dc.type.none.fl_str_mv | Article info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | The influence of adding waste wax, produced as a by-product of the low density polyethylene manufacturing process, on the thermal and mechanical properties of three types of polyethylene (PE), high-density polyethylene (HDPE), linear low-density polyethylene (LLDPE) and low-density polyethylene (LDPE), with 10, 20, 30 and 40wt.% was investigated. Polymer–wax mixing was effective with no apparent leakage of the wax during sample preparation, which was evident from the agreement between the theoretical and experimental values of enthalpy for all types of PE.The wax dispersion in the matrix strongly depends on the percentage of wax added to the polymer and the molecular structure of the polymer. It was found that increasing the wax content enhances the phase separation. LDPE undergoes less phase separation due to its highly branched structure composed of a network of short and long chain branches. The wax has no pronounced plasticising effect on the polymer. This is clearly manifested in LDPE as no change in the melting temperature occurred. LLDPE and HDPE were slightly affected by a high concentration of wax (30% and 40%). This is due to the non-uniform distribution of short chain branching along the LLDPE and HDPE main chains, which can interact with the wax structure. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | qu_f378bc8568b7329f1f18b6a7ae0d7fd6 |
| identifier_str_mv | M.A. AlMaadeed, Sami Labidi, Igor Krupa, Mabrouk Ouederni, Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene, Arabian Journal of Chemistry, Volume 8, Issue 3, May 2015, Pages 388-399. 18785352 388-399 3 8 |
| language_invalid_str_mv | en |
| network_acronym_str | qu |
| network_name_str | Qatar University repository |
| oai_identifier_str | oai:qspace.qu.edu.qa:10576/4766 |
| publishDate | 2015 |
| publisher.none.fl_str_mv | Elsevier B.V. |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | http://creativecommons.org/licenses/by-nc-nd/3.0/ |
| spelling | Effect of waste wax and chain structure on the mechanical and physical properties of polyethyleneAlMaadeed, M.A.Labidi, SamiKrupa, IgorOuederni, MabroukPolyethyleneWaste waxMechanical propertiesThermal propertiesThe influence of adding waste wax, produced as a by-product of the low density polyethylene manufacturing process, on the thermal and mechanical properties of three types of polyethylene (PE), high-density polyethylene (HDPE), linear low-density polyethylene (LLDPE) and low-density polyethylene (LDPE), with 10, 20, 30 and 40wt.% was investigated. Polymer–wax mixing was effective with no apparent leakage of the wax during sample preparation, which was evident from the agreement between the theoretical and experimental values of enthalpy for all types of PE.The wax dispersion in the matrix strongly depends on the percentage of wax added to the polymer and the molecular structure of the polymer. It was found that increasing the wax content enhances the phase separation. LDPE undergoes less phase separation due to its highly branched structure composed of a network of short and long chain branches. The wax has no pronounced plasticising effect on the polymer. This is clearly manifested in LDPE as no change in the melting temperature occurred. LLDPE and HDPE were slightly affected by a high concentration of wax (30% and 40%). This is due to the non-uniform distribution of short chain branching along the LLDPE and HDPE main chains, which can interact with the wax structure.NPRP 4 – 465 – 2 – 173 from Qatar National Research Fund (a member of Qatar Foundation). Open Access funding from King Saud University.Elsevier B.V.2016-09-25T09:39:52Z2015-05Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://dx.doi.org/10.1016/j.arabjc.2014.01.006M.A. AlMaadeed, Sami Labidi, Igor Krupa, Mabrouk Ouederni, Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene, Arabian Journal of Chemistry, Volume 8, Issue 3, May 2015, Pages 388-399.18785352http://www.sciencedirect.com/science/article/pii/S1878535214000094http://hdl.handle.net/10576/4766388-39938enhttp://creativecommons.org/licenses/by-nc-nd/3.0/info:eu-repo/semantics/openAccessoai:qspace.qu.edu.qa:10576/47662024-07-23T15:51:21Z |
| spellingShingle | Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene AlMaadeed, M.A. Polyethylene Waste wax Mechanical properties Thermal properties |
| status_str | publishedVersion |
| title | Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene |
| title_full | Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene |
| title_fullStr | Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene |
| title_full_unstemmed | Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene |
| title_short | Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene |
| title_sort | Effect of waste wax and chain structure on the mechanical and physical properties of polyethylene |
| topic | Polyethylene Waste wax Mechanical properties Thermal properties |
| url | http://dx.doi.org/10.1016/j.arabjc.2014.01.006 http://www.sciencedirect.com/science/article/pii/S1878535214000094 http://hdl.handle.net/10576/4766 |