Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal
Emission from crystalline organic solids is often quenched by nonemissive energy-transfer deexcitation processes. While dispersion of fluorophores in polymers or other hosts has been used to enhance the emission intensity, this strategy results in randomization of guest orientation and optical losse...
محفوظ في:
| المؤلف الرئيسي: | |
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| مؤلفون آخرون: | , , , , , , , |
| منشور في: |
2024
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| الوصول للمادة أونلاين: | https://depot.sorbonne.ae/handle/20.500.12458/1636 |
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| _version_ | 1857415063976017920 |
|---|---|
| author | Commins, Patrick |
| author2 | Al-Handawi, Marieh B. Deger, Caner Polavaram, Srujana Yavuz, Ilhan Rezgui, Rachid Li, Liang Houk, K. N. Naumov, Panče |
| author2_role | author author author author author author author author |
| author_facet | Commins, Patrick Al-Handawi, Marieh B. Deger, Caner Polavaram, Srujana Yavuz, Ilhan Rezgui, Rachid Li, Liang Houk, K. N. Naumov, Panče |
| author_role | author |
| dc.creator.none.fl_str_mv | Commins, Patrick Al-Handawi, Marieh B. Deger, Caner Polavaram, Srujana Yavuz, Ilhan Rezgui, Rachid Li, Liang Houk, K. N. Naumov, Panče |
| dc.date.none.fl_str_mv | 2024-06-25T09:42:37Z 2024-06-25T09:42:37Z 2024 |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | 0002-7863 1520-5126 https://depot.sorbonne.ae/handle/20.500.12458/1636 10.1021/jacs.4c03190 |
| dc.language.none.fl_str_mv | en |
| dc.relation.none.fl_str_mv | Journal of the American Chemical Society |
| dc.title.none.fl_str_mv | Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal |
| dc.type.none.fl_str_mv | Controlled Vocabulary for Resource Type Genres::text::periodical::journal::contribution to journal::journal article |
| description | Emission from crystalline organic solids is often quenched by nonemissive energy-transfer deexcitation processes. While dispersion of fluorophores in polymers or other hosts has been used to enhance the emission intensity, this strategy results in randomization of guest orientation and optical losses at grain boundaries. Here, we report the doping of inherently nonemissive single crystals of anilinium bromide with three fluorescent organic molecules. The doping process equips the crystal with emission characteristics that tune from blue to deep orange. The emission intensity can be reversibly modulated by ferroelastic twinning, which causes the material to function as a multiemissive force sensor. This approach opens up new pathways in the manipulation of emissive properties in organic crystals and may have substantial implications for optoelectronic devices and sensors. |
| id | sorbonner_3bff77ffafbc0017dbc244fc4eb54245 |
| identifier_str_mv | 0002-7863 1520-5126 10.1021/jacs.4c03190 |
| language_invalid_str_mv | en |
| network_acronym_str | sorbonner |
| network_name_str | Sorbonne University Abu Dhabi repository |
| oai_identifier_str | oai:depot.sorbonne.ae:20.500.12458/1636 |
| publishDate | 2024 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| spelling | Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic CrystalCommins, PatrickAl-Handawi, Marieh B.Deger, CanerPolavaram, SrujanaYavuz, IlhanRezgui, RachidLi, LiangHouk, K. N.Naumov, PančeEmission from crystalline organic solids is often quenched by nonemissive energy-transfer deexcitation processes. While dispersion of fluorophores in polymers or other hosts has been used to enhance the emission intensity, this strategy results in randomization of guest orientation and optical losses at grain boundaries. Here, we report the doping of inherently nonemissive single crystals of anilinium bromide with three fluorescent organic molecules. The doping process equips the crystal with emission characteristics that tune from blue to deep orange. The emission intensity can be reversibly modulated by ferroelastic twinning, which causes the material to function as a multiemissive force sensor. This approach opens up new pathways in the manipulation of emissive properties in organic crystals and may have substantial implications for optoelectronic devices and sensors.2024-06-25T09:42:37Z2024-06-25T09:42:37Z2024Controlled Vocabulary for Resource Type Genres::text::periodical::journal::contribution to journal::journal articleapplication/pdf0002-78631520-5126https://depot.sorbonne.ae/handle/20.500.12458/163610.1021/jacs.4c03190enJournal of the American Chemical Societyoai:depot.sorbonne.ae:20.500.12458/16362024-06-25T18:00:36Z |
| spellingShingle | Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal Commins, Patrick |
| title | Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal |
| title_full | Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal |
| title_fullStr | Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal |
| title_full_unstemmed | Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal |
| title_short | Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal |
| title_sort | Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal |
| url | https://depot.sorbonne.ae/handle/20.500.12458/1636 |