Shrinkage, hydration, and strength development of limestone calcined clay cement (LC3) with different sulfation levels

This study investigated autogenous shrinkage of limestone calcined clay cement (LC3)-based mixes with various sulfation levels of hemihydrate. Physicochemical evolution and strength development were also monitored. Superior mechanical performance of the mixes was achieved at an optimal sulfation lev...

Full description

Saved in:
Bibliographic Details
Main Author: Li, Liang (author)
Other Authors: Hay, Rotana (author), Celik, Kemal (author)
Published: 2022
Subjects:
Online Access:https://www.sciencedirect.com/science/article/pii/S0958946521004698?via%3Dihub
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1857415064039981057
author Li, Liang
author2 Hay, Rotana
Celik, Kemal
author2_role author
author
author_facet Li, Liang
Hay, Rotana
Celik, Kemal
author_role author
dc.creator.none.fl_str_mv Li, Liang
Hay, Rotana
Celik, Kemal
dc.date.none.fl_str_mv 2022-02-22T10:00:33Z
2022-02-22T10:00:33Z
2022
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv 10.1016/j.cemconcomp.2021.104403
https://www.sciencedirect.com/science/article/pii/S0958946521004698?via%3Dihub
10.1016/j.cemconcomp.2021.104403
dc.language.none.fl_str_mv en
dc.relation.none.fl_str_mv Cement and Concrete Composites
0958-9465
dc.subject.none.fl_str_mv Limestone calcined clay
Sulfation
Shrinkage
Mechanical properties
dc.title.none.fl_str_mv Shrinkage, hydration, and strength development of limestone calcined clay cement (LC3) with different sulfation levels
dc.type.none.fl_str_mv Controlled Vocabulary for Resource Type Genres::text::periodical::journal::contribution to journal::journal article
description This study investigated autogenous shrinkage of limestone calcined clay cement (LC3)-based mixes with various sulfation levels of hemihydrate. Physicochemical evolution and strength development were also monitored. Superior mechanical performance of the mixes was achieved at an optimal sulfation level, although the shrinkage was reduced with the sulfate content. Calorimetry data showed the hemihydrate delayed and broadened the second aluminate peak. Both gypsum and ettringite formed early during hydration, and carboaluminates were observed after 3 days of curing. Ettringite in the LC3 mixes was of smaller sizes in comparison to that in the ordinary Portland cement (OPC) mixes, attributable to the pore refinement in the LC3 matrices. The content of portlandite (Ca(OH)2) was reduced with the curing time due to pozzolanic reactions. The findings demonstrated a coupling effect of both the chemical and microstructural change on the observed autogenous shrinkage and the consequent performance of LC3-based concrete composites.
id sorbonner_75ec0f0d8907f77f9dab0969ade0d747
identifier_str_mv 10.1016/j.cemconcomp.2021.104403
language_invalid_str_mv en
network_acronym_str sorbonner
network_name_str Sorbonne University Abu Dhabi repository
oai_identifier_str oai:depot.sorbonne.ae:20.500.12458/1248
publishDate 2022
repository.mail.fl_str_mv
repository.name.fl_str_mv
repository_id_str
spelling Shrinkage, hydration, and strength development of limestone calcined clay cement (LC3) with different sulfation levelsLi, LiangHay, RotanaCelik, KemalLimestone calcined claySulfationShrinkageMechanical propertiesThis study investigated autogenous shrinkage of limestone calcined clay cement (LC3)-based mixes with various sulfation levels of hemihydrate. Physicochemical evolution and strength development were also monitored. Superior mechanical performance of the mixes was achieved at an optimal sulfation level, although the shrinkage was reduced with the sulfate content. Calorimetry data showed the hemihydrate delayed and broadened the second aluminate peak. Both gypsum and ettringite formed early during hydration, and carboaluminates were observed after 3 days of curing. Ettringite in the LC3 mixes was of smaller sizes in comparison to that in the ordinary Portland cement (OPC) mixes, attributable to the pore refinement in the LC3 matrices. The content of portlandite (Ca(OH)2) was reduced with the curing time due to pozzolanic reactions. The findings demonstrated a coupling effect of both the chemical and microstructural change on the observed autogenous shrinkage and the consequent performance of LC3-based concrete composites.2022-02-22T10:00:33Z2022-02-22T10:00:33Z2022Controlled Vocabulary for Resource Type Genres::text::periodical::journal::contribution to journal::journal articleapplication/pdf10.1016/j.cemconcomp.2021.104403https://www.sciencedirect.com/science/article/pii/S0958946521004698?via%3Dihub10.1016/j.cemconcomp.2021.104403enCement and Concrete Composites0958-9465oai:depot.sorbonne.ae:20.500.12458/12482022-11-28T06:39:22Z
spellingShingle Shrinkage, hydration, and strength development of limestone calcined clay cement (LC3) with different sulfation levels
Li, Liang
Limestone calcined clay
Sulfation
Shrinkage
Mechanical properties
title Shrinkage, hydration, and strength development of limestone calcined clay cement (LC3) with different sulfation levels
title_full Shrinkage, hydration, and strength development of limestone calcined clay cement (LC3) with different sulfation levels
title_fullStr Shrinkage, hydration, and strength development of limestone calcined clay cement (LC3) with different sulfation levels
title_full_unstemmed Shrinkage, hydration, and strength development of limestone calcined clay cement (LC3) with different sulfation levels
title_short Shrinkage, hydration, and strength development of limestone calcined clay cement (LC3) with different sulfation levels
title_sort Shrinkage, hydration, and strength development of limestone calcined clay cement (LC3) with different sulfation levels
topic Limestone calcined clay
Sulfation
Shrinkage
Mechanical properties
url https://www.sciencedirect.com/science/article/pii/S0958946521004698?via%3Dihub