Strategies to Diversification of the Mechanical Properties of Organic Crystals
Structurally ordered soft materials that respond to complementary stimuli are susceptible to control over their spatial and temporal morphostructural configurations by intersectional or combined effects such as gating, feedback, shape-memory, or programming. In the absence of general and robust desi...
محفوظ في:
| المؤلف الرئيسي: | |
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| مؤلفون آخرون: | , , , , , , , , , , |
| منشور في: |
2024
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| الوصول للمادة أونلاين: | https://depot.sorbonne.ae/handle/20.500.12458/1635 |
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| _version_ | 1857415063569170432 |
|---|---|
| author | Dai, Shuting |
| author2 | Zhong, Jiangbin Yang, Xiqiao Chen, Chao Zhou, Liping Liu, Xinyu Sun, Jingbo Ye, Kaiqi Zhang, Hongyu Li, Liang Naumov, Panče Lu, Ran |
| author2_role | author author author author author author author author author author author |
| author_facet | Dai, Shuting Zhong, Jiangbin Yang, Xiqiao Chen, Chao Zhou, Liping Liu, Xinyu Sun, Jingbo Ye, Kaiqi Zhang, Hongyu Li, Liang Naumov, Panče Lu, Ran |
| author_role | author |
| dc.creator.none.fl_str_mv | Dai, Shuting Zhong, Jiangbin Yang, Xiqiao Chen, Chao Zhou, Liping Liu, Xinyu Sun, Jingbo Ye, Kaiqi Zhang, Hongyu Li, Liang Naumov, Panče Lu, Ran |
| dc.date.none.fl_str_mv | 2024-06-25T09:30:58Z 2024-06-25T09:30:58Z 2024 |
| dc.identifier.none.fl_str_mv | 0044-8249 1521-3757 https://depot.sorbonne.ae/handle/20.500.12458/1635 10.1002/ange.202320223 |
| dc.language.none.fl_str_mv | en |
| dc.relation.none.fl_str_mv | Angewandte Chemie |
| dc.title.none.fl_str_mv | Strategies to Diversification of the Mechanical Properties of Organic Crystals |
| dc.type.none.fl_str_mv | Controlled Vocabulary for Resource Type Genres::text::periodical::journal::contribution to journal::journal article |
| description | Structurally ordered soft materials that respond to complementary stimuli are susceptible to control over their spatial and temporal morphostructural configurations by intersectional or combined effects such as gating, feedback, shape-memory, or programming. In the absence of general and robust design and prediction strategies for their mechanical properties, at present, combined chemical and crystal engineering approaches could provide useful guidelines to identify effectors that determine both the magnitude and time of their response. Here, we capitalize on the purported ability of soft intermolecular interactions to instigate mechanical compliance by using halogenation to elicit both mechanical and photochemical activity of organic crystals. Starting from (E)-1,4-diphenylbut-2-ene-1,4-dione, whose crystals are brittle and photoinert, we use double and quadruple halogenation to introduce halogen-bonded planes that become interfaces for molecular gliding, rendering the material mechanically and photochemically plastic. Fluorination diversifies the mechanical effects further, and crystals of the tetrafluoro derivative are not only elastic but also motile, displaying the rare photosalient effect. |
| id | sorbonner_76a3f4a3e2fc92afc2ce11f4c0f92f15 |
| identifier_str_mv | 0044-8249 1521-3757 10.1002/ange.202320223 |
| language_invalid_str_mv | en |
| network_acronym_str | sorbonner |
| network_name_str | Sorbonne University Abu Dhabi repository |
| oai_identifier_str | oai:depot.sorbonne.ae:20.500.12458/1635 |
| publishDate | 2024 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| spelling | Strategies to Diversification of the Mechanical Properties of Organic CrystalsDai, ShutingZhong, JiangbinYang, XiqiaoChen, ChaoZhou, LipingLiu, XinyuSun, JingboYe, KaiqiZhang, HongyuLi, LiangNaumov, PančeLu, RanStructurally ordered soft materials that respond to complementary stimuli are susceptible to control over their spatial and temporal morphostructural configurations by intersectional or combined effects such as gating, feedback, shape-memory, or programming. In the absence of general and robust design and prediction strategies for their mechanical properties, at present, combined chemical and crystal engineering approaches could provide useful guidelines to identify effectors that determine both the magnitude and time of their response. Here, we capitalize on the purported ability of soft intermolecular interactions to instigate mechanical compliance by using halogenation to elicit both mechanical and photochemical activity of organic crystals. Starting from (E)-1,4-diphenylbut-2-ene-1,4-dione, whose crystals are brittle and photoinert, we use double and quadruple halogenation to introduce halogen-bonded planes that become interfaces for molecular gliding, rendering the material mechanically and photochemically plastic. Fluorination diversifies the mechanical effects further, and crystals of the tetrafluoro derivative are not only elastic but also motile, displaying the rare photosalient effect.2024-06-25T09:30:58Z2024-06-25T09:30:58Z2024Controlled Vocabulary for Resource Type Genres::text::periodical::journal::contribution to journal::journal article0044-82491521-3757https://depot.sorbonne.ae/handle/20.500.12458/163510.1002/ange.202320223enAngewandte Chemieoai:depot.sorbonne.ae:20.500.12458/16352024-06-25T09:30:58Z |
| spellingShingle | Strategies to Diversification of the Mechanical Properties of Organic Crystals Dai, Shuting |
| title | Strategies to Diversification of the Mechanical Properties of Organic Crystals |
| title_full | Strategies to Diversification of the Mechanical Properties of Organic Crystals |
| title_fullStr | Strategies to Diversification of the Mechanical Properties of Organic Crystals |
| title_full_unstemmed | Strategies to Diversification of the Mechanical Properties of Organic Crystals |
| title_short | Strategies to Diversification of the Mechanical Properties of Organic Crystals |
| title_sort | Strategies to Diversification of the Mechanical Properties of Organic Crystals |
| url | https://depot.sorbonne.ae/handle/20.500.12458/1635 |