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    A 100,000-Fold Increase in C–H Bond Acidity Gives Palladium a Key Advantage in C(sp<sup>3</sup>)–H Activation Compared to Nickel by Lirong Lin (10158818)

    Published 2025
    “…This work presents the first direct measurements of C(sp<sup>3</sup>)–H bond acidity (p<i>K</i><sub>a</sub>) and bond dissociation free energy (BDFE) for a species containing a ligated alkane–palladium interaction (R<sub>2</sub>CH<sub>2</sub>···Pd), also known as an agostic interaction. …”
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