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Large Hyperfine Coupling Arising from Pseudo‑<sup>2</sup>S Ground States in a Series of Lutetium(II) Metallocene Complexes
Published 2025“…Moreover, an extremely large splitting of the eight-line spectra indicates the presence of strong hyperfine coupling, and simulations provide isotropic hyperfine coupling constants of <i>A</i><sub>iso</sub> = 4.38, 4.30, and 4.17 GHz across the series, where the value of <i>A</i><sub>iso</sub> is found to decrease as the Cp–Lu–Cp angle becomes more acute. …”