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Cobalt-Complexed Acetylenic Tetrads, a Molecular Scaffold for Quadruple Ionic Functionalization Reactions
Published 2024“…A methodology was developed for introducing nucleophiles into the α- and α′-positions of the dicobalt hexacarbonyl-complexed acetylenic tetrads. A synthetic algorithm included the entry of a given nucleophile to both termini of the acetylenic tetrad <b>A</b> (α-Nu<sup>1</sup>-α′-Nu<sup>1</sup>; α-Nu<sup>2</sup>-α′-Nu<sup>2</sup>), or a pair of select nucleophiles arranged unsymmetrically in opposing sequences (α-Nu<sup>1</sup>-α′-Nu<sup>2</sup>; α-Nu<sup>2</sup>-α′-Nu<sup>1</sup>). …”
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