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    Multi-State Redox and Light-Driven Switching of Pseudorotaxanation and Cation Shuttling by Robert Hein (4849108)

    Published 2025
    “…Specifically, the neutral switches can be quantitatively converted between <i>anti-</i> and <i>syn-</i>folded receptor geometries by irradiation, leading to the discovery of a significant increase or decrease in cation binding affinity, which was exploited to shuttle the pseudorotaxane-forming dibenzylammonium guest between the switchable crown ethers of slightly different sizes. …”
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