Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Relevance modulated retention of picture-locations associations. by Eelco V. van Dongen (93251)

DataSheet1_Binary Mixtures of Imidazolium-Based Protic Ionic Liquids. Extended Temperature Range of the Liquid State Keeping High Ionic Conductivities.PDF by Iqbaal Abdurrokhman (6649952)

“…The activation energy, E_a, estimated by fitting with the Arrhenius relation in a limited temperature range (between 60 and 140 °C) varies marginally and keeps values between 0.17 and 0.21 eV. …”

Nuclear arms races: Experimental evolution for mating success in the mushroom-forming fungus <i>Schizophyllum commune</i> by Bart P. S. Nieuwenhuis (6160661)

“…Even though only two of those five remained significant after correcting for multiple comparisons, for all five lines we found a correlation between the efficiency with which the female mycelium is accessed and fitness, providing additional circumstantial evidence for fitness change in those five lines. …”

Functional Characterization of AbeD, an RND-Type Membrane Transporter in Antimicrobial Resistance in <i>Acinetobacter baumannii</i> by Vijaya Bharathi Srinivasan (148478)

“…</p><p>Results</p><p>The <i>abeD</i> mutant displayed ~ 3.37 fold decreased survival and >5-fold reduced growth in hostile osmotic (0.25 M; NaCl) and oxidative (2.631 μM–6.574 μM; H₂O₂) stress conditions respectively. …”

DataSheet1_Tomographic Image of Shear Wave Structure of NE India Based on Analysis of Rayleigh Wave Data.PDF by Amit Kumar (81180)

“…The images obtained reveal a very complicated tectonic regime. The Bengal Basin comprises a thick layer of sediments with the thickness increasing from west to east and a sudden steepening of the basement on the eastern side of the Eocene Hinge zone. …”

DataSheet_1_Metabolome analysis reveals flavonoid changes during the leaf color transition in Populus × euramericana ‘Zhonghuahongye’.zip by Mengjiao Chen (6560651)

“…</p>Results<p>The a*, C* and chromatic light values of the leaves decreased by 108.91%, 52.08% and 113.34%, while the brightness L values and chromatic b* values gradually increased by 36.01% and 13.94%, respectively. …”

Data_Sheet_1_Reproductive-dependent effects of B vitamin deficiency on lifespan and physiology.PDF by Guixiang Yu (17273653)

“…Notably, the dietary absence of VB₁, VB₃, VB₅, VB₆, or VB₇ significantly decreased the lifespan of wild-type females, yet demonstrated relatively little effect on ovo^D1 infertile mutant females’ lifespan. …”

Phenotypic diversity of starch pasting properties in cassava for food industry by Cristiano Silva dos Santos (11985971)

“…The lowest Bayesian information criterion identified five different groups. Groups 3 and 4 exhibited high pasting temperatures, while Groups 3 and 5 exhibited low setbacks. …”

DataSheet2_Tomographic Image of Shear Wave Structure of NE India Based on Analysis of Rayleigh Wave Data.pdf by Amit Kumar (81180)

“…The images obtained reveal a very complicated tectonic regime. The Bengal Basin comprises a thick layer of sediments with the thickness increasing from west to east and a sudden steepening of the basement on the eastern side of the Eocene Hinge zone. …”

Electromechanical Properties and Spontaneous Response of the Current in InAsP Nanowires by Jong Hoon Lee (245610)

“…We found that the electronic transport of the InAsP NWs is dominated by space-charge-limited transport, with a <i>I</i> ∞ <i>V</i>² relation. Upon increasing the tensile strain, the electrical current in the NWs increases linearly, and the piezoresistance gradually decreases nonlinearly. …”

Undernutrition and obesity trends in Brazilian adults from 1975 to 2019 and its associated factors by Wolney Lisboa Conde (7316525)

“…From 1975 to 2019 underweight has decreased from 9.1% to 2.5% among men and 12.2% to 3.4% among women. …”

Deletion of Dicer in Smooth Muscle Affects Voiding Pattern and Reduces Detrusor Contractility and Neuroeffector Transmission by Mardjaneh Karbalaei Sadegh (168255)

“…Furthermore, electrical field stimulation revealed a decreased cholinergic but maintained purinergic component of neurogenic activation in Dicer KO bladder strips. …”

Carbonic Anhydrase Generates CO₂ and H⁺ That Drive Spider Silk Formation Via Opposite Effects on the Terminal Domains by Marlene Andersson (610369)

“…Surprisingly, the terminal domains respond in opposite ways when pH is decreased from 7 to 5: Urea denaturation and temperature stability assays show that NT dimers get significantly stabilized and then lock the spidroins into multimers, whereas CT on the other hand is destabilized and unfolds into ThT-positive β-sheet amyloid fibrils, which can trigger fiber formation. …”

Hydrogen in Drinking Water Reduces Dopaminergic Neuronal Loss in the 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine Mouse Model of Parkinson's Disease by Kyota Fujita (258978)

“…The concentration-dependency of H₂ showed that H₂ as low as 0.08 ppm had almost the same effect as saturated H₂ water (1.5 ppm). MPTP-induced accumulation of cellular 8-oxoguanine (8-oxoG), a marker of DNA damage, and 4-hydroxynonenal (4-HNE), a marker of lipid peroxidation were significantly decreased in the nigro-striatal dopaminergic pathway in mice drinking H₂-containing water, whereas production of superoxide (O₂•⁻) detected by intravascular injection of dihydroethidium (DHE) was not reduced significantly. …”