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Competitive C−H Bond Activation and β-Hydride Elimination at Platinum(II)
Published 2007“…Thermolysis of the five-coordinate Pt(IV) complex (AnIm)Pt(CH<sub>3</sub>)<sub>3</sub> (<b>1b</b>) (AnIm = [<i>o-</i>C<sub>6</sub>H<sub>4</sub>{N(C<sub>6</sub>H<sub>3</sub><i><sup>i</sup></i><sup></sup>Pr<sub>2</sub>)}(CH=NC<sub>6</sub>H<sub>3</sub><i><sup>i</sup></i><sup></sup>Pr<sub>2</sub>)]<sup>-</sup>) in benzene-<i>d</i><sub>6</sub> at 60 °C yields a new Pt(II) olefin hydride complex (<b>2b</b>-<b><i>d</i></b><b><sub>27</sub></b>). …”
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113000
Competitive C−H Bond Activation and β-Hydride Elimination at Platinum(II)
Published 2007“…Thermolysis of the five-coordinate Pt(IV) complex (AnIm)Pt(CH<sub>3</sub>)<sub>3</sub> (<b>1b</b>) (AnIm = [<i>o-</i>C<sub>6</sub>H<sub>4</sub>{N(C<sub>6</sub>H<sub>3</sub><i><sup>i</sup></i><sup></sup>Pr<sub>2</sub>)}(CH=NC<sub>6</sub>H<sub>3</sub><i><sup>i</sup></i><sup></sup>Pr<sub>2</sub>)]<sup>-</sup>) in benzene-<i>d</i><sub>6</sub> at 60 °C yields a new Pt(II) olefin hydride complex (<b>2b</b>-<b><i>d</i></b><b><sub>27</sub></b>). …”