Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Image8_Aurantii fructus immaturus carbonisata-derived carbon dots and their anti-depression effect.TIF by Xiaopeng Li (496883)

“…Aurantii Fructus Immaturus (AFI) has a rich historical legacy in Traditional Chinese Medicine (TCM) for its traditional use as a treatment for depression. …”

Data_Sheet_1_EEG response of dexmedetomidine during drug induced sleep endoscopy.PDF by Lichy Han (294140)

“…</p>Results<p>Our pharmacokinetic model yielded a two-compartment model with volumes of 51.8 L and 106.2 L, with clearances of 69.5 and 168.9 L/h, respectively, and a time to effect of 9 min, similar to prior studies. …”

Attenuation of Renovascular Damage in Zucker Diabetic Fatty Rat by NWT-03, an Egg Protein Hydrolysate with ACE- and DPP4-Inhibitory Activity by Yumei Wang (128815)

“…Neither NWT-03 nor VIL improved metabolic parameters; for VIL, this was despite a 5-fold increase in glucagon-like peptide (GLP)-1 levels. …”

Image_1_Relevance of PSGL-1 Expression in B Cell Development and Activation.jpeg by Rafael González-Tajuelo (2562418)

“…In the spleen of WT mice, the highest percentages of PSGL-1⁺ populations were shown by Breg (90%), B1a (34.7%), and B1b (19.1%), while only 2.5–8% of B2 cells expressed PSGL-1; however, within B2 cells, the class-switched subsets showed the highest percentages of PSGL-1⁺ cells. …”

Reference standards for lean mass measures using GE dual energy x-ray absorptiometry in Caucasian adults by Mary T. Imboden (3937946)

“…</p><p>Results</p><p>Men had higher mean total LM, %LM, LMI, and ALMI than women (p<0.01), across all age groups. All LM variables decreased significantly over the 5 decades in men, however in women only total LM, %LM, and ALMI decreased from the youngest to oldest age groups (p<0.01).…”

Image6_Aurantii fructus immaturus carbonisata-derived carbon dots and their anti-depression effect.JPEG by Xiaopeng Li (496883)

“…Aurantii Fructus Immaturus (AFI) has a rich historical legacy in Traditional Chinese Medicine (TCM) for its traditional use as a treatment for depression. …”

Image7_Aurantii fructus immaturus carbonisata-derived carbon dots and their anti-depression effect.JPEG by Xiaopeng Li (496883)

“…Aurantii Fructus Immaturus (AFI) has a rich historical legacy in Traditional Chinese Medicine (TCM) for its traditional use as a treatment for depression. …”

Image4_Aurantii fructus immaturus carbonisata-derived carbon dots and their anti-depression effect.JPEG by Xiaopeng Li (496883)

“…Aurantii Fructus Immaturus (AFI) has a rich historical legacy in Traditional Chinese Medicine (TCM) for its traditional use as a treatment for depression. …”

Image3_Aurantii fructus immaturus carbonisata-derived carbon dots and their anti-depression effect.JPEG by Xiaopeng Li (496883)

“…Aurantii Fructus Immaturus (AFI) has a rich historical legacy in Traditional Chinese Medicine (TCM) for its traditional use as a treatment for depression. …”

Allergenic food introduction and risk of childhood atopic diseases by Niels J. Elbert (4620823)

“…</p><p>Materials and methods</p><p>This study among 5,202 children was performed in a population-based prospective cohort. …”