Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Effect of ALA, DHA, EPA, LA, AA, GLA and 5-FU on the expression of PGDS and mPGES in RKO cells by ELISA. by Chengcheng Zhang (725743)

Effect of aplysin on plasma endotoxin levels, intestinal mucosal barrier function and cytokines. by Meilan Xue (310911)

“…<p>A) The level of plasma endotoxin in rats. B) The level of plasma DAO in rats. …”

Drug trends among non-institutionalized Canadians and the impact of data collection changes in the Canadian Health Measures Survey 2007 to 2015 by Yi-Sheng Chao (4383916)

“…The total numbers of medications were asked in all cycles. However, only a maximum of 15 and 5 drugs could be respectively reported for existing and new prescription or OTC drugs in cycles 1 and 2. …”

Phenotypic subgrouping and multi-omics analyses reveal reduced diazepam-binding inhibitor (DBI) protein levels in autism spectrum disorder with severe language impairment by Chatravee Pichitpunpong (6524255)

“…Proteome profiling of lymphoblastoid cell lines from these individuals was performed via 2D-gel electrophoresis, and then mass spectrometry. …”

Progesterone reduced LPS-mediated phosphorylation of P38, JNK and ERK MAPKs. by Beilei Lei (449125)

Ct values do not differ substantially by vaccine type. by Kasen K. Riemersma (5434607)

“…</b> The time analysis showed a decrease in N1 Ct values with time over 7 months. …”

S1 Dataset - by Justin M. Gregory (9640145)

“…<div><p>This study examined the impact of a hypercaloric high-fat high-fructose diet (HFFD) in dogs as a potential model for human impaired glucose tolerance (IGT) and type 2 diabetes mellitus (T2DM). …”

Experimental timeline. by Justin M. Gregory (9640145)

“…<div><p>This study examined the impact of a hypercaloric high-fat high-fructose diet (HFFD) in dogs as a potential model for human impaired glucose tolerance (IGT) and type 2 diabetes mellitus (T2DM). …”

Novel Allosteric Inhibitors of Deoxyhypusine Synthase against Malignant Melanoma: Design, Synthesis, and Biological Evaluation by Kai-li Liu (11378101)

“…Furthermore, by western blot analysis, compound <b>8m</b> effectively activated caspase 3 and decreased the expressions of GP-100, tyrosinase, eIF5A2, MMP2, and MMP9. …”

New Arylpiperazines as Potent and Selective Dopamine D4 Receptor Ligands Potentially Useful to Treat Glioblastoma by Federica Matteucci (4353835)

“…In this article, new piperazine ligands, analogues of the potent and selective D4R lead compounds <b>9</b> and <b>10</b>, were prepared and evaluated for their affinity at D2-like receptor subtypes. The most promising results were obtained by replacing the N4-phenyl terminal of <b>9</b> with a naphthyl group. …”

Novel Allosteric Inhibitors of Deoxyhypusine Synthase against Malignant Melanoma: Design, Synthesis, and Biological Evaluation by Kai-li Liu (11378101)

“…Furthermore, by western blot analysis, compound <b>8m</b> effectively activated caspase 3 and decreased the expressions of GP-100, tyrosinase, eIF5A2, MMP2, and MMP9. …”

Novel Allosteric Inhibitors of Deoxyhypusine Synthase against Malignant Melanoma: Design, Synthesis, and Biological Evaluation by Kai-li Liu (11378101)

“…Furthermore, by western blot analysis, compound <b>8m</b> effectively activated caspase 3 and decreased the expressions of GP-100, tyrosinase, eIF5A2, MMP2, and MMP9. …”

Novel Allosteric Inhibitors of Deoxyhypusine Synthase against Malignant Melanoma: Design, Synthesis, and Biological Evaluation by Kai-li Liu (11378101)

“…Furthermore, by western blot analysis, compound <b>8m</b> effectively activated caspase 3 and decreased the expressions of GP-100, tyrosinase, eIF5A2, MMP2, and MMP9. …”

Relationship between serum progesterone levels and top-quality blastocyst formation rate. by V. S. Vanni (4030871)

“…<p>With an increase in progesterone levels at induction, a decrease in top-quality blastocyst is observed. …”

Behavioral classification of animals with the FULL and ECO models. by Naëmi Kuehn (17310359)