Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster by Dmitrii S. Bolotin (1953220)

“…The results of DFT calculations indicate that the mechanism for these reactions is stepwise and is realized through the formation of the orientation complex of the nitrone form, R²R³CN⁺­(H)­O^–, of oximes with [B₁₀H₉­NCEt]⁻, giving further an acyclic intermediate (the rate-determining step), followed by proton migration, leading to the addition product. …”

Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster by Dmitrii S. Bolotin (1953220)

“…The results of DFT calculations indicate that the mechanism for these reactions is stepwise and is realized through the formation of the orientation complex of the nitrone form, R²R³CN⁺­(H)­O^–, of oximes with [B₁₀H₉­NCEt]⁻, giving further an acyclic intermediate (the rate-determining step), followed by proton migration, leading to the addition product. …”

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