Showing 521 - 540 results of 102,420 for search '(( 2 step decrease ) OR ( 5 ((((fold decrease) OR (point decrease))) OR (a decrease)) ))', query time: 1.42s Refine Results
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    Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster by Dmitrii S. Bolotin (1953220)

    Published 2016
    “…The results of DFT calculations indicate that the mechanism for these reactions is stepwise and is realized through the formation of the orientation complex of the nitrone form, R<sup>2</sup>R<sup>3</sup>CN<sup>+</sup>­(H)­O<sup>–</sup>, of oximes with [B<sub>10</sub>H<sub>9</sub>­NCEt]<sup>−</sup>, giving further an acyclic intermediate (the rate-determining step), followed by proton migration, leading to the addition product. …”
  11. 531

    Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster by Dmitrii S. Bolotin (1953220)

    Published 2016
    “…The results of DFT calculations indicate that the mechanism for these reactions is stepwise and is realized through the formation of the orientation complex of the nitrone form, R<sup>2</sup>R<sup>3</sup>CN<sup>+</sup>­(H)­O<sup>–</sup>, of oximes with [B<sub>10</sub>H<sub>9</sub>­NCEt]<sup>−</sup>, giving further an acyclic intermediate (the rate-determining step), followed by proton migration, leading to the addition product. …”
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    Fig 5 - by David Mathar (9707947)

    Published 2022
    Subjects:
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    S5 Fig - by David Mathar (9707947)

    Published 2022
    Subjects:
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