Showing 381 - 400 results of 134,989 for search '(( 2 we decrease ) OR ( 5 ((((non decrease) OR (point decrease))) OR (a decrease)) ))', query time: 1.91s Refine Results
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    Influence of Thiolate Ligands on Reductive N−O Bond Activation. Probing the O<sub>2</sub><sup>−</sup> Binding Site of a Biomimetic Superoxide Reductase Analogue and Examining the P... by Gloria Villar-Acevedo (2232583)

    Published 2011
    “…Like NO-bound <i>trans</i>-cysteinate-ligated SOR (SOR-NO), the rhombic <i>S</i> = 3/2 EPR signal of NO-bound <i>cis</i>-thiolate-ligated [Fe(S<sup>Me<sub>2</sub></sup>N<sub>4</sub>(tren)(NO)]<sup>+</sup> (<b>2</b>; <i>g</i> = 4.44, 3.54, 1.97), the isotopically sensitive ν<sub>NO</sub>(ν<sub><sup>15</sup>NO</sub>) stretching frequency (1685(1640) cm<sup>−1</sup>), and the 0.05 Å decrease in Fe−S bond length are shown to be consistent with <i>the oxidative addition of NO to Fe(II)</i> to afford an Fe(III)−NO<sup>−</sup> {FeNO}<sup>7</sup> species containing high-spin (<i>S</i> = 5/2) Fe(III) antiferromagnetically coupled to NO<sup>−</sup> (<i>S</i> = 1). …”
  7. 387

    Influence of Thiolate Ligands on Reductive N−O Bond Activation. Probing the O<sub>2</sub><sup>−</sup> Binding Site of a Biomimetic Superoxide Reductase Analogue and Examining the P... by Gloria Villar-Acevedo (2232583)

    Published 2011
    “…Like NO-bound <i>trans</i>-cysteinate-ligated SOR (SOR-NO), the rhombic <i>S</i> = 3/2 EPR signal of NO-bound <i>cis</i>-thiolate-ligated [Fe(S<sup>Me<sub>2</sub></sup>N<sub>4</sub>(tren)(NO)]<sup>+</sup> (<b>2</b>; <i>g</i> = 4.44, 3.54, 1.97), the isotopically sensitive ν<sub>NO</sub>(ν<sub><sup>15</sup>NO</sub>) stretching frequency (1685(1640) cm<sup>−1</sup>), and the 0.05 Å decrease in Fe−S bond length are shown to be consistent with <i>the oxidative addition of NO to Fe(II)</i> to afford an Fe(III)−NO<sup>−</sup> {FeNO}<sup>7</sup> species containing high-spin (<i>S</i> = 5/2) Fe(III) antiferromagnetically coupled to NO<sup>−</sup> (<i>S</i> = 1). …”
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    Hydroxyl Defects in LiFePO<sub>4</sub> Cathode Material: DFT+<i>U</i> and an Experimental Study by Dmitry A. Aksyonov (4918594)

    Published 2021
    “…Using a combined computational and experimental approach comprising density functional theory (DFT)+<i>U</i> and molecular dynamics calculations and X-ray and neutron diffraction, we provide a comprehensive characterization of various OH point defects in LiFePO<sub>4</sub>, including their formation, dynamics, and localization in the interstitial space and at Li, Fe, and P sites. …”
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    Data_Sheet_1_Pulmonary inflammation decreases with ultra-protective ventilation in experimental ARDS under VV-ECMO: a positron emission tomography study.docx by Guillaume Deniel (17990323)

    Published 2024
    “…However, whether these strategies reduce lung inflammation more effectively than protective ventilation (PV) remains unclear. We aimed to demonstrate that a UPV strategy decreases acute lung inflammation in comparison with PV in an experimental swine model of ARDS.…”
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