Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Photoinduced Rearrangement of Aromatic <i>N</i>-Chloroamides to Chloroaromatic Amides in the Solid State: Inverted Π_N–Σ_N Occupational Stability of Amidyl Radi... by Panče Naumov (1474312)

“…Thorough theoretical modeling of the factors determinant to the stability and the nature of the spin-hosting orbital evidenced that although the <i>trans</i>-Π_|| state (N<i>p</i> spin) of the amidyls is normally preferred over the <i>trans</i>-Σ_⊥ configuration (N<i>sp</i>² spin), stabilization by aromatic conjugation, steric and geometry factors, as well as by electronic effects from the substituents can decrease the Π–Σ gap in these intermediates significantly, resulting in similar and, in the case of the orthogonal amide-phenyl disposition, even reversed population of the unpaired electron in the two orbitals. …”

Relative permeability curve of a well in Gudong test area. by Mengyun Li (7490870)

Dose-Finding Study of Omeprazole on Gastric pH in Neonates with Gastro-Esophageal Acid Reflux Using a Bayesian Sequential Approach by Florentia Kaguelidou (373190)

“…</p><p>Results</p><p>Fifty-four neonates with a reflux index ranging from 5.06 to 27.7% were included. …”

Mechanoresponsive Spin via Spin–Lattice Coupling in Organic Cocrystals by Zhiyan Chen (6369101)

“…The response of crystal structure to external stimuli provides potential applications in the areas of detection, diagnosis, and repair. In this work, we fabricate two allotropic organic cocrystals, with different space groups and lattice parameters, with identical donor and acceptor molecules inside them. …”

Mechanoresponsive Spin via Spin–Lattice Coupling in Organic Cocrystals by Zhiyan Chen (6369101)

“…The response of crystal structure to external stimuli provides potential applications in the areas of detection, diagnosis, and repair. In this work, we fabricate two allotropic organic cocrystals, with different space groups and lattice parameters, with identical donor and acceptor molecules inside them. …”

Numbers of new neurons in HVC as a function of hemisphere and experimental condition. by Jake V. Aronowitz (11361921)

Performance accuracy in the spatial discrimination task, in terms of mean errors from 5 trials of a single session. by Wiâm Ramadan (371049)

Image_2_IRE1α-XBP1 Affects the Mitochondrial Function of Aβ25–35-Treated SH-SY5Y Cells by Regulating Mitochondria-Associated Endoplasmic Reticulum Membranes.TIF by Bingcong Chu (10431125)

“…Cells were collected and analyzed by Western blotting, quantitative real-time PCR, electron microscopy, fluorescence microscopy, calcium imaging, and other biochemical assays.</p><p>Results: Aβ-exposed SH-SY5Y cells showed an increased expression of XBP1s and p-IRE1α. 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) and calcium imaging analysis showed that the IRE1α inhibitor, 4μ8c, reduced Aβ-induced cytotoxicity. …”

Period and velocity of PeCoWaCo are stable across a broad range of cell sizes. by Özge Özgüç (12290245)

Disparities in Hemoglobin A1c Testing During the Transition to Adulthood and Association With Diabetes Outcomes in Youth-Onset Type 1 and Type 2 Diabetes: The SEARCH for Diabetes i... by Katherine A Sauder (11126343)

“…HbA1c testing ≥3 times/year over time was associated with lower HbA1c levels (-0.36% [-0.65 to -0.06]) and lower odds of microvascular complications (OR 0.64 [0.43-0.97]) at 13 years duration, but associations were attenuated after adjustment for HbA1c testing correlates (-0.17 [-0.46 to 0.13]); OR 0.70 [0.46-1.07], respectively). For type 2 diabetes, not seeing an endocrinologist decreased odds of reporting ≥3 HbA1c tests/year over time (OR 0.19 [0.06-0.63]), but HbA1c testing frequency was not associated with HbA1c levels or microvascular complications.…”

Table 1_Altered gut microbiome in convalescent patients with coronavirus disease 2019.docx by Kyoung Hwa Lee (8906261)

“…Additionally, we were able to detect microbiome changes in patients who were re-infected with SARS-CoV-2. …”

Image 1_Altered gut microbiome in convalescent patients with coronavirus disease 2019.tif by Kyoung Hwa Lee (8906261)

“…Additionally, we were able to detect microbiome changes in patients who were re-infected with SARS-CoV-2. …”

Effect of Cytosolic pH on Inward Currents Reveals Structural Characteristics of the Proton Transport Cycle in the Influenza A Protein M2 in Cell-Free Membrane Patches of <i>Xenopus... by Mattia L. DiFrancesco (364045)

“…<div><p>Transport activity through the mutant D44A of the M2 proton channel from influenza virus A was measured in excised inside-out macro-patches of <i>Xenopus laevis</i> oocytes at cytosolic pH values of 5.5, 7.5 and 8.2. …”