Showing 221 - 240 results of 100,766 for search '(( 5 ((((nm decrease) OR (a decrease))) OR (nn decrease)) ) OR ( 2 step decrease ))', query time: 1.26s Refine Results
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    Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster by Dmitrii S. Bolotin (1953220)

    Published 2016
    “…The results of DFT calculations indicate that the mechanism for these reactions is stepwise and is realized through the formation of the orientation complex of the nitrone form, R<sup>2</sup>R<sup>3</sup>CN<sup>+</sup>­(H)­O<sup>–</sup>, of oximes with [B<sub>10</sub>H<sub>9</sub>­NCEt]<sup>−</sup>, giving further an acyclic intermediate (the rate-determining step), followed by proton migration, leading to the addition product. …”
  3. 223

    Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster by Dmitrii S. Bolotin (1953220)

    Published 2016
    “…The results of DFT calculations indicate that the mechanism for these reactions is stepwise and is realized through the formation of the orientation complex of the nitrone form, R<sup>2</sup>R<sup>3</sup>CN<sup>+</sup>­(H)­O<sup>–</sup>, of oximes with [B<sub>10</sub>H<sub>9</sub>­NCEt]<sup>−</sup>, giving further an acyclic intermediate (the rate-determining step), followed by proton migration, leading to the addition product. …”
  4. 224

    Fig 5 - by David Mathar (9707947)

    Published 2022
    Subjects:
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    S5 Fig - by David Mathar (9707947)

    Published 2022
    Subjects:
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