Search alternatives:
step decrease » sizes decrease (Expand Search), teer decrease (Expand Search), we decrease (Expand Search)
nm decrease » _ decrease (Expand Search), we decrease (Expand Search), gy decreased (Expand Search)
nn decrease » _ decrease (Expand Search), mean decrease (Expand Search), gy decreased (Expand Search)
a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
2 step » _ step (Expand Search), a step (Expand Search)
step decrease » sizes decrease (Expand Search), teer decrease (Expand Search), we decrease (Expand Search)
nm decrease » _ decrease (Expand Search), we decrease (Expand Search), gy decreased (Expand Search)
nn decrease » _ decrease (Expand Search), mean decrease (Expand Search), gy decreased (Expand Search)
a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
2 step » _ step (Expand Search), a step (Expand Search)
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Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster
Published 2016“…The results of DFT calculations indicate that the mechanism for these reactions is stepwise and is realized through the formation of the orientation complex of the nitrone form, R<sup>2</sup>R<sup>3</sup>CN<sup>+</sup>(H)O<sup>–</sup>, of oximes with [B<sub>10</sub>H<sub>9</sub>NCEt]<sup>−</sup>, giving further an acyclic intermediate (the rate-determining step), followed by proton migration, leading to the addition product. …”
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Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster
Published 2016“…The results of DFT calculations indicate that the mechanism for these reactions is stepwise and is realized through the formation of the orientation complex of the nitrone form, R<sup>2</sup>R<sup>3</sup>CN<sup>+</sup>(H)O<sup>–</sup>, of oximes with [B<sub>10</sub>H<sub>9</sub>NCEt]<sup>−</sup>, giving further an acyclic intermediate (the rate-determining step), followed by proton migration, leading to the addition product. …”
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