Showing 941 - 960 results of 102,157 for search '(( 5 ((((nn decrease) OR (a decrease))) OR (mean decrease)) ) OR ( 2 step decrease ))', query time: 1.69s Refine Results
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    Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster by Dmitrii S. Bolotin (1953220)

    Published 2016
    “…The results of DFT calculations indicate that the mechanism for these reactions is stepwise and is realized through the formation of the orientation complex of the nitrone form, R<sup>2</sup>R<sup>3</sup>CN<sup>+</sup>­(H)­O<sup>–</sup>, of oximes with [B<sub>10</sub>H<sub>9</sub>­NCEt]<sup>−</sup>, giving further an acyclic intermediate (the rate-determining step), followed by proton migration, leading to the addition product. …”
  16. 956

    Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster by Dmitrii S. Bolotin (1953220)

    Published 2016
    “…The results of DFT calculations indicate that the mechanism for these reactions is stepwise and is realized through the formation of the orientation complex of the nitrone form, R<sup>2</sup>R<sup>3</sup>CN<sup>+</sup>­(H)­O<sup>–</sup>, of oximes with [B<sub>10</sub>H<sub>9</sub>­NCEt]<sup>−</sup>, giving further an acyclic intermediate (the rate-determining step), followed by proton migration, leading to the addition product. …”
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