Mechanistic Investigation of the Hydrogenation of Ketones Catalyzed by a Ruthenium(II) Complex Featuring an N-Heterocyclic Carbene with a Tethered Primary Amine Donor: Evidence for... by Wylie W. N. O (1755865)

“…On the other hand, the energy barriers for an inner-sphere mechanism involving the decoordination of the amine group of the NHC ligand, the heterolytic splitting of dihydrogen across a Ru−O(alkoxide) bond, and hydride migration to the coordinated ketone, are respectively 15.5, 17.5, and 15.6 kcal/mol uphill at 298 K and 1 atm. …”

Mechanistic Investigation of the Hydrogenation of Ketones Catalyzed by a Ruthenium(II) Complex Featuring an N-Heterocyclic Carbene with a Tethered Primary Amine Donor: Evidence for... by Wylie W. N. O (1755865)

“…On the other hand, the energy barriers for an inner-sphere mechanism involving the decoordination of the amine group of the NHC ligand, the heterolytic splitting of dihydrogen across a Ru−O(alkoxide) bond, and hydride migration to the coordinated ketone, are respectively 15.5, 17.5, and 15.6 kcal/mol uphill at 298 K and 1 atm. …”

Mechanistic Investigation of the Hydrogenation of Ketones Catalyzed by a Ruthenium(II) Complex Featuring an N-Heterocyclic Carbene with a Tethered Primary Amine Donor: Evidence for... by Wylie W. N. O (1755865)

“…On the other hand, the energy barriers for an inner-sphere mechanism involving the decoordination of the amine group of the NHC ligand, the heterolytic splitting of dihydrogen across a Ru−O(alkoxide) bond, and hydride migration to the coordinated ketone, are respectively 15.5, 17.5, and 15.6 kcal/mol uphill at 298 K and 1 atm. …”

<i>OsNF-YAs</i> RNAi mutants are more resistant to viruses. by Xiaoxiang Tan (12542842)

Pharmacologiic Inhibition of protein kinase A improved antioxidant activities in endothelial cells. by Zhaoyun Zhang (118032)

“…C: Catalase activity increase. D: ROS level decrease. E: TBARs level decrease. *, p<0.05 compared with 25 mM condition. #, p<0.05 compared with 5.6 mM condition. n = 8.…”

Ku0063794 and temsirolimus inhibited tumor growth in a xenograft model of RCC. by Hao Zhang (15339)

“…<p>(<b>A</b>) The treatment with Ku0063794 or temsirolimus significantly inhibited tumor growth in Nu/Nu nude mice. …”

Collecting data from a woodlot of York University (Keele campus) by Melinaz_ Barati (3118581)

“…Vertebrates and invertebrates were observed, using a naked eye. For invertebrates, the length of the transect was shortened to a 5 meter radius. …”

OsNF-YAs negatively modulate rice resistance to RSV and SRBSDV. by Xiaoxiang Tan (12542842)

Raw data. by Dominic Michael Rasp (19959412)

“…Our new instruction and variables (Fz_VH, Fres_VH, M_F_ortho_VH) showed better validity (mean r = 0.77, r = 0.81, and r = 0.85) and equally good or better reliability (ICCs: 0.87, 0.89, and 0.94; CVs: 4.7%, 4.1%, and 4.7%) than the original instruction and variable (Fz_V) (mean r = 0.70; ICC: 0.91; CV: 5.6%). There were no differences in muscle activities between the variables and instructions of the 90:20 IPCT. …”

A20 protects GSCs from TNFα-induced apoptosis. by Anita B. Hjelmeland (104655)

“…<p>(A and B) The percentage of Annexin V–positive cells increases with TNFα treatment of non-stem glioma cells, but not matched GSC-enriched cultures, isolated from a D456MG (A) or a T3359 (B) patient specimen passaged short term in immunocompromised mice. …”

A Spectroscopic Study of OB Stars Located in the Outer Galactic Disk by Gustavo Bragança (98330)

“…We have obtained high-resolution, echelle spectra for a sample of 137 OB stars located towards the Galactic anticenter using the 6.5m Magellan Clay telescope + MIKE spectrograph. …”

CyberKnife radiation therapy as a platform for translational mouse studies by Martha Kiljan (10885523)

“…<p>Radiation therapy (RT) is a common nonsurgical treatment in the management of patients with cancer. …”

Dose–response relationship between IBL, OS (a), and RFS (b). by Wu Jiang (189621)

Data_Sheet_1_Multiple treatment interruptions and protecting HIV-specific CD4 T cells enable durable CD8 T cell response and viral control.PDF by Anshika Jain (8037536)

“…The patients reached a viral set point ranging from 7,000 copies/mL to 25,000 copies/mL. …”

A proposed model of distinctive Src activities at different subcellular locations. by Qiaoqiao Wan (621794)

MRI scans of a four-month child with CHIKV neonatal encephalopathy. by Patrick Gérardin (95836)

“…<p>- Child n°4 of <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0002996#pntd-0002996-t005" target="_blank">Table 5</a>. …”

S1 Data - by Guoqing Meng (4669774)

“…Additionally, mice in the PRE and POS groups showed significantly increased levels of IL-10 (<i>P</i> < 0.01), and significantly decreased levels of IL-5, IL-13, MCP-1, eotaxin, and tumor necrosis factor-α (<i>P</i> < 0.01).…”

Differential counts of leukocytes in mouse BALF. by Guoqing Meng (4669774)

“…Additionally, mice in the PRE and POS groups showed significantly increased levels of IL-10 (<i>P</i> < 0.01), and significantly decreased levels of IL-5, IL-13, MCP-1, eotaxin, and tumor necrosis factor-α (<i>P</i> < 0.01).…”

Supplementary Material for: Cryosurgery as a Single Agent and in Combination with Intralesional Corticosteroids Is Effective on Young, Small Keloids and Induces Characteristic Hist... by Zouboulis C.C. (2917943)

“…Median lesional volumes decreased from 106 to 7 mm³ in group A (<i>p</i> = 0.001) and from 138 to 6 mm³ in group B (<i>p</i> < 0.0001; ns, between groups). …”

DataSheet1_ERK1/2 regulates melanin synthesis in fish: a case study on a colourful variety, leopard coral grouper (Plectropomus leopardus).zip by Min Yang (146229)

“…The research team conducted a combined transcriptomic and proteomic analysis of P. leopardus skin tissues in red-skinned and black-skinned fish and found that the common differences were reflected in the melanogenesis pathway. …”