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    Structure, Insertion Electrochemistry, and Magnetic Properties of a New Type of Substitutional Solid Solutions of Copper, Nickel, and Iron Hexacyanoferrates/Hexacyanocobaltates by Antje Widmann (2966013)

    Published 2002
    “…The dependencies of lattice parameters on composition exhibit in all series of solid solutions studied similar, although small, deviations from ideality, which correlate with the electrochemical behavior. Finally, a series of solid solutions of the composition KNi<sub>0.5</sub><sup>II</sup>Cu<sub>0.5</sub><sup>II</sup>[Fe<sup>III</sup>(CN)<sub>6</sub>]<sub>1</sub><sub>-</sub><i><sub>x</sub></i>[Co<sup>III</sup>(CN)<sub>6</sub>]<i><sub>x</sub></i>, where both the nitrogen- and carbon-coordinated metal ions are mixed populated and were synthesized and characterized. …”
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