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Showing 20,861 - 20,862 results of 20,862 for search '(( 5 ((ng decrease) OR (nn decrease)) ) OR ( 100 ((nm decrease) OR (a decrease)) ))', query time: 0.43s Refine Results
  1. 20861
    Reductive Cleavage of Acyl Halides to Carboxylato Alkylidyne Complexes from Their Reactions with the Quintuply Bonded Dimolybdenum Amidinate

    Reductive Cleavage of Acyl Halides to Carboxylato Alkylidyne Complexes from Their Reactions with the Quintuply Bonded Dimolybdenum Amidinate by N. V. Satyachand Harisomayajula (2611348)

    Published 2016
    “…DFT calculations on Mo<sub>2</sub>(Cl)­(μ-κ<sup>2</sup>-OCMe)­[μ-κ<sup>2</sup>-HC­(N-2,6-<sup><i>i</i></sup>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)<sub>2</sub>]<sub>2</sub> suggested that it equilibrates with the oxo alkylidyne Mo<sub>2</sub>(O)­(μ-Cl)­(μ-CMe)­[μ-κ<sup>2</sup>-HC­(N-2,6-<sup><i>i</i></sup>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)<sub>2</sub>]<sub>2</sub> in a ratio of about 100:1. The nucleophilic MoO functionality turned out to be reactive toward various electrophiles. …”
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  2. 20862
    Reductive Cleavage of Acyl Halides to Carboxylato Alkylidyne Complexes from Their Reactions with the Quintuply Bonded Dimolybdenum Amidinate

    Reductive Cleavage of Acyl Halides to Carboxylato Alkylidyne Complexes from Their Reactions with the Quintuply Bonded Dimolybdenum Amidinate by N. V. Satyachand Harisomayajula (2611348)

    Published 2016
    “…DFT calculations on Mo<sub>2</sub>(Cl)­(μ-κ<sup>2</sup>-OCMe)­[μ-κ<sup>2</sup>-HC­(N-2,6-<sup><i>i</i></sup>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)<sub>2</sub>]<sub>2</sub> suggested that it equilibrates with the oxo alkylidyne Mo<sub>2</sub>(O)­(μ-Cl)­(μ-CMe)­[μ-κ<sup>2</sup>-HC­(N-2,6-<sup><i>i</i></sup>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)<sub>2</sub>]<sub>2</sub> in a ratio of about 100:1. The nucleophilic MoO functionality turned out to be reactive toward various electrophiles. …”
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