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point decrease » point increase (Expand Search)
non decrease » note decreased (Expand Search), fold decrease (Expand Search), mean decrease (Expand Search)
nn decrease » _ decrease (Expand Search), mean decrease (Expand Search), gy decreased (Expand Search)
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18561
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18562
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18563
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18564
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18565
Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>‑Heterocyclic Carbene Complexes: A Combined X‑ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach
Published 2020“…The binding situation in the corresponding cationic complexes Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)(NHC)(OC(CF<sub>3</sub>)<sub>3</sub>)<sup>+</sup> B(Ar<sup>F</sup>)<sub>4</sub><sup>–</sup> (NHC = IMes (<b>1</b>), IMesCl<sub>2</sub> (<b>2</b>), IMesMe<sub>2</sub> (<b>3</b>), and IMesH<sub>2</sub> (<b>4</b>) was compared to that of the analogous neutral Schrock catalyst Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)((OC(CF<sub>3</sub>)<sub>3</sub>))<sub>2</sub> (<b>5</b>). Single-crystal X-ray data were used as a starting point for the optimization of the geometries of the catalysts at the PBE0-D3BJ/def2-SVP level of theory; the obtained data were compared to those obtained from X-ray absorption (XAS) and emission spectroscopy (XES). …”
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18566
Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>‑Heterocyclic Carbene Complexes: A Combined X‑ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach
Published 2020“…The binding situation in the corresponding cationic complexes Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)(NHC)(OC(CF<sub>3</sub>)<sub>3</sub>)<sup>+</sup> B(Ar<sup>F</sup>)<sub>4</sub><sup>–</sup> (NHC = IMes (<b>1</b>), IMesCl<sub>2</sub> (<b>2</b>), IMesMe<sub>2</sub> (<b>3</b>), and IMesH<sub>2</sub> (<b>4</b>) was compared to that of the analogous neutral Schrock catalyst Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)((OC(CF<sub>3</sub>)<sub>3</sub>))<sub>2</sub> (<b>5</b>). Single-crystal X-ray data were used as a starting point for the optimization of the geometries of the catalysts at the PBE0-D3BJ/def2-SVP level of theory; the obtained data were compared to those obtained from X-ray absorption (XAS) and emission spectroscopy (XES). …”
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18567
Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>‑Heterocyclic Carbene Complexes: A Combined X‑ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach
Published 2020“…The binding situation in the corresponding cationic complexes Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)(NHC)(OC(CF<sub>3</sub>)<sub>3</sub>)<sup>+</sup> B(Ar<sup>F</sup>)<sub>4</sub><sup>–</sup> (NHC = IMes (<b>1</b>), IMesCl<sub>2</sub> (<b>2</b>), IMesMe<sub>2</sub> (<b>3</b>), and IMesH<sub>2</sub> (<b>4</b>) was compared to that of the analogous neutral Schrock catalyst Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)((OC(CF<sub>3</sub>)<sub>3</sub>))<sub>2</sub> (<b>5</b>). Single-crystal X-ray data were used as a starting point for the optimization of the geometries of the catalysts at the PBE0-D3BJ/def2-SVP level of theory; the obtained data were compared to those obtained from X-ray absorption (XAS) and emission spectroscopy (XES). …”
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18568
Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>‑Heterocyclic Carbene Complexes: A Combined X‑ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach
Published 2020“…The binding situation in the corresponding cationic complexes Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)(NHC)(OC(CF<sub>3</sub>)<sub>3</sub>)<sup>+</sup> B(Ar<sup>F</sup>)<sub>4</sub><sup>–</sup> (NHC = IMes (<b>1</b>), IMesCl<sub>2</sub> (<b>2</b>), IMesMe<sub>2</sub> (<b>3</b>), and IMesH<sub>2</sub> (<b>4</b>) was compared to that of the analogous neutral Schrock catalyst Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)((OC(CF<sub>3</sub>)<sub>3</sub>))<sub>2</sub> (<b>5</b>). Single-crystal X-ray data were used as a starting point for the optimization of the geometries of the catalysts at the PBE0-D3BJ/def2-SVP level of theory; the obtained data were compared to those obtained from X-ray absorption (XAS) and emission spectroscopy (XES). …”
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18569
Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>‑Heterocyclic Carbene Complexes: A Combined X‑ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach
Published 2020“…The binding situation in the corresponding cationic complexes Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)(NHC)(OC(CF<sub>3</sub>)<sub>3</sub>)<sup>+</sup> B(Ar<sup>F</sup>)<sub>4</sub><sup>–</sup> (NHC = IMes (<b>1</b>), IMesCl<sub>2</sub> (<b>2</b>), IMesMe<sub>2</sub> (<b>3</b>), and IMesH<sub>2</sub> (<b>4</b>) was compared to that of the analogous neutral Schrock catalyst Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)((OC(CF<sub>3</sub>)<sub>3</sub>))<sub>2</sub> (<b>5</b>). Single-crystal X-ray data were used as a starting point for the optimization of the geometries of the catalysts at the PBE0-D3BJ/def2-SVP level of theory; the obtained data were compared to those obtained from X-ray absorption (XAS) and emission spectroscopy (XES). …”
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18570
Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>‑Heterocyclic Carbene Complexes: A Combined X‑ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach
Published 2020“…The binding situation in the corresponding cationic complexes Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)(NHC)(OC(CF<sub>3</sub>)<sub>3</sub>)<sup>+</sup> B(Ar<sup>F</sup>)<sub>4</sub><sup>–</sup> (NHC = IMes (<b>1</b>), IMesCl<sub>2</sub> (<b>2</b>), IMesMe<sub>2</sub> (<b>3</b>), and IMesH<sub>2</sub> (<b>4</b>) was compared to that of the analogous neutral Schrock catalyst Mo(<i>N</i>-2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHCMe<sub>2</sub>Ph)((OC(CF<sub>3</sub>)<sub>3</sub>))<sub>2</sub> (<b>5</b>). Single-crystal X-ray data were used as a starting point for the optimization of the geometries of the catalysts at the PBE0-D3BJ/def2-SVP level of theory; the obtained data were compared to those obtained from X-ray absorption (XAS) and emission spectroscopy (XES). …”
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18571
HbA1c Reduction in Dulaglutide-Treated Patients Irrespective of Duration of Diabetes, Microvascular Disease, and BMI: A Post Hoc Analysis From the REWIND Trial
Published 2022“…</p> <p><b>Conclusions:</b> Dulaglutide 1.5 mg treatment was statistically associated with a long-lasting decrease in HbA1c over 72 months, irrespective of baseline duration of diabetes, microvascular disease, and BMI.…”
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18572
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18573
μCT analysis of organotypic cultured embryonic femurs (E13) in basal and TGF-β3 conditions.
Published 2015“…<p><i>A</i>, μCT images (whole femur tissue; saggital sections; segmented mineralized bone (green); and cross sectional sections of the central diaphysis region) of the embryonic chick femurs (E13) organotypic cultured in basal and TGF-β3 (5ng/ml and 15ng/ml) for 10 days. …”
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18574
Supplementary Material for: Decreasing Trend in Incidence of Late Onset Culture Positive Bloodstream Infections but Not Late Onset Meningitis in Preterm Infants <33 Weeks Gestation...
Published 2021“…<b><i>Conclusions:</i></b> There was a decreasing trend of late onset CPBSI but not late onset meningitis. …”
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18575
<i>TWIST1</i> knockdown activates senescence in human non-small cell lung cancer cells.
Published 2012“…<p>Three different shRNAs were able to knockdown <i>TWIST1</i> mRNA levels and result in decreased TWIST1 protein in the <i>KRAS</i> mutated non-small cell lung cancer (NSCLC) cell line H460 as shown by (A) qPCR and (B) TWIST1 Western blotting on day 9 after the shRNA infection. …”
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18576
Muscle differentiation genes are regulated by laminin α5 chain.
Published 2012“…<p>(A) Semi-quantitative RT-PCR experiments were performed on E15.5 control and knockout intestines for genes belonging to the muscle compartment. …”
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18577
Molecular manipulation of AQP5 altered the MT soluble fraction.
Published 2013“…<p>A. Transduction of adeno-AQP5 in 16HBE cells led to a significant decrease in soluble tubulin fraction. …”
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18578
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18579
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18580
Synthesis, Anti-HIV Activity, and Metabolic Stability of New Alkenyldiarylmethane HIV-1 Non-Nucleoside Reverse Transcriptase Inhibitors
Published 2005“…Their stabilities in rat plasma have also been investigated. Although introducing 5-chloro-2-methoxyphenyl or 3-fluoro-5-trifluoromethylphenyl groups into alkenyldiarylmethanes does not maintain the antiviral potency, the structural modification of alkenyldiarylmethanes with a 3-cyanophenyl substituent can be made without a large decrease in activity. …”