Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Effect of Oxidation and Protonation States on [2Fe–2S] Cluster Nitrosylation Giving {Fe(NO)₂}⁹ Dinitrosyl Iron Complexes (DNICs) by Christine E. Schiewer (6112373)

“…Density functional theory calculations based on the structure of <b>3</b>^<b>–</b> indicate that the electronic ground-state properties of <b>3</b>^<b>–</b> and <b>3H</b> are similar, although the NO­(π*) → Fe 3d π-donation is slightly increased and π-backbonding is slightly decreased upon protonation. As a result, protonation has a significant effect on the NO stretching frequencies, but only minor effects on the Fe–(NO)₂ modes. …”

Mannitol uptake is repressed in vitro, but mannitol reaches <i>S</i>Tm inside host cells without affecting the host or bacterial metabolism. by Karin Mitosch (16851651)

“…<i>p</i>-values are highly significant (8.3·10^-7 and 6.5·10^-4) from a two-sample <i>t</i> test. …”

Elucidating the survival and response of carbapenem resistant <i>Klebsiella pneumoniae</i> after exposure to imipenem at sub-lethal concentrations by Ye Mun Low (5917862)

Table_1_The Impact of Gut Microbiome on Metabolic Disorders During Catch-Up Growth in Small-for-Gestational-Age.docx by Jingjing An (10228238)

“…Transcriptomic data revealed that insulin-like growth factor-2 expression was significantly decreased in CUG-SGA rats and was associated with a decrease in Lactobacillus bacteria.…”

<i>Haemophilus influenzae</i> type b disease in the era of conjugate vaccines: critical factors for successful eradication by Mary Slack (9506663)

“…<p>Prior to implementation of <i>Haemophilus influenzae</i> type b (Hib)-conjugate vaccination programs in the 1990s, Hib was the commonest cause of bacterial meningitis in children aged <5 years. While the burden of all Hib disease has significantly decreased in the post-vaccination era, Hib still accounted for >29,000 deaths worldwide in children aged <5 years in 2015.…”

BRCA1 protein levels are altered by γ irradiation. by Weijun Liu (233776)

“…<p><b>A</b>. BRCA1 protein levels rapidly drop in response to γ irradiation in HeLa cells. …”

Impact of <i>luxR</i> complementation on bioluminescene during long term culturing of <i>Vibrio fischeri</i>. by Grace Chong (423249)

“…<p>Relative bioluminescence output from the dark <i>V. fischeri</i> MJ1 Lineage 10 with a <i>luxR</i> mutation complimented with a functional <i>luxR</i> gene under control of its own promoter on pLS6luxR. …”

Genetic screen in haploid ESCs for PMP resistance identifies Anoikis modulators. by Giulio Di Minin (4768200)

“…<b>(B)</b> SAG and PMP decrease survival of ESCs treated for 48 hours with SΗΗ (50 to 500 ng/ml), SAG (0.5 to 5 μM), PMP (1 to 10 μM), Cyclopamine-KAAD (1 to 5 μM), and SANT-1 (10 to 50 μM). …”