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  1. 225341

    Imido Transfer from Bis(imido)ruthenium(VI) Porphyrins to Hydrocarbons:  Effect of Imido Substituents, C−H Bond Dissociation Energies, and Ru<sup>VI/V</sup> Reduction Potentials... by Sarana Ka-Yan Leung (2661700)

    Published 2005
    “…The second-order rate constants (<i>k</i><sub>2</sub>) of the aziridination/amidation reactions at 298 K were determined to be (2.6 ± 0.1) × 10<sup>-5</sup> to 14.4 ± 0.6 dm<sup>3</sup> mol<sup>-1</sup> s<sup>-1</sup>, which generally increase with increasing Ru<sup>VI/V</sup> reduction potential of the imido complexes and decreasing C−H bond dissociation energy (BDE) of the hydrocarbons. …”
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