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step decrease » sizes decrease (Expand Search), teer decrease (Expand Search)
we decrease » _ decrease (Expand Search), nn decrease (Expand Search), teer decrease (Expand Search)
a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
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225341
Imido Transfer from Bis(imido)ruthenium(VI) Porphyrins to Hydrocarbons: Effect of Imido Substituents, C−H Bond Dissociation Energies, and Ru<sup>VI/V</sup> Reduction Potentials...
Published 2005“…The second-order rate constants (<i>k</i><sub>2</sub>) of the aziridination/amidation reactions at 298 K were determined to be (2.6 ± 0.1) × 10<sup>-5</sup> to 14.4 ± 0.6 dm<sup>3</sup> mol<sup>-1</sup> s<sup>-1</sup>, which generally increase with increasing Ru<sup>VI/V</sup> reduction potential of the imido complexes and decreasing C−H bond dissociation energy (BDE) of the hydrocarbons. …”
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