Combined Experimental and Computational Studies on Carbon−Carbon Reductive Elimination from Bis(hydrocarbyl) Complexes of (PCP)Ir by Rajshekhar Ghosh (1812388)

“…C−C elimination from complexes with the common d⁶ six-coordinate configuration generally proceeds via prior ligand loss, which greatly complicates any attempt to directly measure the rates of the specific elimination step. We report the synthesis of a series of five-coordinate d⁶ iridium complexes, (^tBuPCP)Ir(R)(R′), where R and R′ are Me, Ph, and (phenyl-substituted) vinyl and alkynyl groups. …”

Combined Experimental and Computational Studies on Carbon−Carbon Reductive Elimination from Bis(hydrocarbyl) Complexes of (PCP)Ir by Rajshekhar Ghosh (1812388)

“…C−C elimination from complexes with the common d⁶ six-coordinate configuration generally proceeds via prior ligand loss, which greatly complicates any attempt to directly measure the rates of the specific elimination step. We report the synthesis of a series of five-coordinate d⁶ iridium complexes, (^tBuPCP)Ir(R)(R′), where R and R′ are Me, Ph, and (phenyl-substituted) vinyl and alkynyl groups. …”

Combined Experimental and Computational Studies on Carbon−Carbon Reductive Elimination from Bis(hydrocarbyl) Complexes of (PCP)Ir by Rajshekhar Ghosh (1812388)

“…C−C elimination from complexes with the common d⁶ six-coordinate configuration generally proceeds via prior ligand loss, which greatly complicates any attempt to directly measure the rates of the specific elimination step. We report the synthesis of a series of five-coordinate d⁶ iridium complexes, (^tBuPCP)Ir(R)(R′), where R and R′ are Me, Ph, and (phenyl-substituted) vinyl and alkynyl groups. …”

Combined Experimental and Computational Studies on Carbon−Carbon Reductive Elimination from Bis(hydrocarbyl) Complexes of (PCP)Ir by Rajshekhar Ghosh (1812388)

“…C−C elimination from complexes with the common d⁶ six-coordinate configuration generally proceeds via prior ligand loss, which greatly complicates any attempt to directly measure the rates of the specific elimination step. We report the synthesis of a series of five-coordinate d⁶ iridium complexes, (^tBuPCP)Ir(R)(R′), where R and R′ are Me, Ph, and (phenyl-substituted) vinyl and alkynyl groups. …”

Combined Experimental and Computational Studies on Carbon−Carbon Reductive Elimination from Bis(hydrocarbyl) Complexes of (PCP)Ir by Rajshekhar Ghosh (1812388)

“…C−C elimination from complexes with the common d⁶ six-coordinate configuration generally proceeds via prior ligand loss, which greatly complicates any attempt to directly measure the rates of the specific elimination step. We report the synthesis of a series of five-coordinate d⁶ iridium complexes, (^tBuPCP)Ir(R)(R′), where R and R′ are Me, Ph, and (phenyl-substituted) vinyl and alkynyl groups. …”

Image_3_Genetic Deficiency of p53 Leads to Structural, Functional, and Synaptic Deficits in Primary Somatosensory Cortical Neurons of Adult Mice.TIF by Haixia Kuang (5864108)

“…We found that the spiking frequency, excitatory inputs, and sag ratio were decreased in L5 pyramidal neurons of p53KO mice. …”

Image_1_Genetic Deficiency of p53 Leads to Structural, Functional, and Synaptic Deficits in Primary Somatosensory Cortical Neurons of Adult Mice.TIF by Haixia Kuang (5864108)

“…We found that the spiking frequency, excitatory inputs, and sag ratio were decreased in L5 pyramidal neurons of p53KO mice. …”

Image_4_Genetic Deficiency of p53 Leads to Structural, Functional, and Synaptic Deficits in Primary Somatosensory Cortical Neurons of Adult Mice.TIF by Haixia Kuang (5864108)

“…We found that the spiking frequency, excitatory inputs, and sag ratio were decreased in L5 pyramidal neurons of p53KO mice. …”

Image_2_Genetic Deficiency of p53 Leads to Structural, Functional, and Synaptic Deficits in Primary Somatosensory Cortical Neurons of Adult Mice.TIF by Haixia Kuang (5864108)

“…We found that the spiking frequency, excitatory inputs, and sag ratio were decreased in L5 pyramidal neurons of p53KO mice. …”

DataSheet_1_Nationwide Trends of Pediatric Obesity and BMI z-Score From 2017-2021 in China: Comparable Findings From Real-World Mobile- and Hospital-Based Data.docx by Yan Yang (33204)

“…The trend of obesity prevalence remained stable with slight decrease, but COVID-19 lockdown caused a significant increase of 1.86% in 2020. …”

Kinetics of differential gene expression after rapid degradation of endogenous OGT in MEFs. by Sara Formichetti (20536052)

“…Differentially expressed genes with p-value < 10⁻⁵ and absolute log₂FC > 0.3 (i.e. 1.2-fold increase or decrease in expression) are colored in red and their number is indicated. …”

Chile’s 2014 sugar-sweetened beverage tax and changes in prices and purchases of sugar-sweetened beverages: An observational study in an urban environment by Juan Carlos Caro (4707607)

“…The volume of household purchases of L-SSBs increased 10.7% (95% CI 7.5%–13.9%), while that of untaxed beverage purchases decreased by 3.1% (95% CI −5.1%–−1.1%). …”

Replacement of chicken skin with canola oil in chicken nuggets by Sandra Tiemi Seó (16453032)

“…The pH values ranged from 6.62 to 6.86, as an effect of frying, there was an increase in lipid content with increasing levels of substitution (T0-raw: 5.36% and fried: 12.11%; T100-raw: 7.93% and fried: 15.43%) and a decrease in moisture content in relation to the raw sample. …”

Production and characterization of gypsum-based composites reinforced with cocoa agroindustry waste particles by Maria Cecíllia Ramos de Araújo Veloso (10472934)

“…It was found that there were improvements in physical properties with the addition of reinforcement making the material lighter, given the reduction in density (1190.69 to 1138.92 kg/m³), ??and providing a decrease in hygroscopicity, with moisture levels decreasing from 7.74 to 4.01% and water absorption decreasing from 18.37 to 5.28%. …”

MSc Dissertation Figures by Bianca Diedericks (17370739)

“…</p><p dir="ltr">Figure 3: Euclea natalensis: (A) Tree, (B) Fruits, and (C) Flowers.</p><p dir="ltr">Figure 4: Chemical structure: (A) 7-Methyljuglone and (B) Diospyrin</p><p dir="ltr">Figure 5: The postulated mechanism of action of 7-methyljuglone which will disrupt the electron transport chain and therefore decrease or stop the electron flow in the bacterium.…”

<i>In cellulo</i> Evaluation of Phototransformation Quantum Yields in Fluorescent Proteins Used As Markers for Single-Molecule Localization Microscopy by Sergiy Avilov (575857)

“…To this aim, we developed a data processing strategy based on the clustering optimization procedure proposed by Lee et al (PNAS 109, 17436–17441, 2012). …”

Data_Sheet_1_Present and future distribution of Faidherbia albida in Cabo Verde as revealed by climatic modelling and LULC analysis.PDF by Danilson Varela (14799583)

“…On average, the predicted suitable habitat for future distributions gradually decreases by 2080 under both scenarios compared with the current, with a smaller effect of RCP4.5 than of RCP8.5. …”

Table_1_Age-Related Structural and Functional Changes in the Mouse Lung.DOCX by Henri Schulte (8078324)

“…While the alveolar number decreased from young (7.5 × 10⁶) to middle-aged (6 × 10⁶) and increased again in old (9 × 10⁶) mice, the mean alveolar volume and mean septal surface area per alveolus conversely first increased in middle-aged and then declined in old mice. …”

<i>TcPiezo-CKO</i> responses to hypoosmotic stress. by Guozhong Huang (673424)

“…(D) Tet-induced <i>TcPiezo2 Tet-OFF</i> cells (+Tet) had a significant decrease of intracellular Ca²⁺ rise, compared to non-induced cells (-Tet). 100 µ M EGTA was added to remove extracellular Ca^2<i>+</i>, abolishing Ca²⁺ entry, as indicated. …”

Table_1_miR-212 and miR-132 Are Downregulated in Neurally Derived Plasma Exosomes of Alzheimer’s Patients.XLSX by Diana J. Cha (8041226)

“…ROC analysis indicated that measurement of miR-132-3p in neurally-derived plasma EVs showed good sensitivity and specificity to diagnose AD, but did not effectively separate individuals with AD-MCI from controls. Moreover, when we measured the levels of a related miRNA, miR-212, we found that this miRNA was also decreased in neural EVs from AD patients compared to controls. …”