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    140 H/D Isotopomers Identified by Long-Range NMR Hyperfine Shifts in Ruthenium(III) Ammine Complexes. Hyperconjugation in Ru–NH<sub>3</sub> Bonding by W. Michael Laidlaw (1947022)

    Published 2013
    “…We analyze the origin of this remarkable sensitivity, which relies on the favorable characteristics of the Ru<sup>III</sup> low-spin t<sub>2g</sub><sup>5</sup> configuration, having a spin–orbit coupling constant ζ ≈ 950 cm<sup>–1</sup>.…”
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