Stable Mononuclear, 17-Electron Molybdenum(III) Carbonyl Complexes. Synthesis, Structure, Thermal Decomposition, and Cl^- Addition Reactions by James C. Fettinger (1312290)

“…The four-legged piano stool geometry of <b>2</b>⁺ with the phosphines atoms in relative <i>cis</i> positions has been confirmed by a single-crystal X-ray analysis. The X-ray data for [<b>2</b>]PF₆·THF are the following:  monoclinic, <i>P</i>2₁/<i>n</i>, <i>a</i> = 13.7394(14) Å, <i>b</i> = 20.421(2) Å, <i>c </i>= 14.857(2) Å, β = 99.119(8)°, <i>V</i> = 4115.8(8) ų, <i>Z</i> = 4, <i>D</i><i>_x</i> = 1.469 g·cm^-3, λ(Mo Kα) = 0.71073 Å, μ (Mo Kα) = 0.562 mm^-1, <i>R</i>(<i>F</i>) = 4.59%, <i>R</i>(<i>wF</i>²) = 10.77% for 4299 data with <i>F</i>_o > 4σ(<i>F</i>_o). …”

Stable Mononuclear, 17-Electron Molybdenum(III) Carbonyl Complexes. Synthesis, Structure, Thermal Decomposition, and Cl^- Addition Reactions by James C. Fettinger (1312290)

“…The four-legged piano stool geometry of <b>2</b>⁺ with the phosphines atoms in relative <i>cis</i> positions has been confirmed by a single-crystal X-ray analysis. The X-ray data for [<b>2</b>]PF₆·THF are the following:  monoclinic, <i>P</i>2₁/<i>n</i>, <i>a</i> = 13.7394(14) Å, <i>b</i> = 20.421(2) Å, <i>c </i>= 14.857(2) Å, β = 99.119(8)°, <i>V</i> = 4115.8(8) ų, <i>Z</i> = 4, <i>D</i><i>_x</i> = 1.469 g·cm^-3, λ(Mo Kα) = 0.71073 Å, μ (Mo Kα) = 0.562 mm^-1, <i>R</i>(<i>F</i>) = 4.59%, <i>R</i>(<i>wF</i>²) = 10.77% for 4299 data with <i>F</i>_o > 4σ(<i>F</i>_o). …”

Single-cell-resolution analysis of RPE flatmounts revealed only minor changes to cellular morphology. by Viola Kretschmer (485828)

“…Analysis of cell size revealed a modest increase in cell size in the mutant starting from P29 onwards, while AR was decreasing. …”