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    Stereoelectronic Effects in Cl<sub>2</sub> Elimination from Binuclear Pt(III) Complexes by David C. Powers (1345497)

    Published 2016
    “…Transient absorption spectroscopy, steady-state photocrystallography, and far-infrared vibrational spectroscopy suggest a halogen elimination mechanism that proceeds via two sequential halogen-atom-extrusion steps. Solution-phase calorimetry experiments of the meridional complexes have defined the thermodynamics of halogen elimination, which show a decrease in the photoelimination quantum efficiency with an increase in the thermochemically defined Pt–X bond strength. …”
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