Showing 12,161 - 12,180 results of 140,532 for search '(( 50 ((nn decrease) OR (a decrease)) ) OR ( 10 ((we decrease) OR (mean decrease)) ))', query time: 1.40s Refine Results
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    Experimental and Computational Insight into the Mechanism of NO Binding to Ferric Microperoxidase. The Likely Role of Tautomerization to Account for the pH Dependence by Maria Oszajca (1833010)

    Published 2021
    “…From the pH dependence of the second-order rate constant for NO binding (<i>k</i><sub>on</sub>), we determined individual rate constants characterizing forms <b>1</b>–<b>3</b>, revealing only a ca. 10-fold decrease in the NO binding rate on going from <b>1</b> (<i>k</i><sub>on</sub><sup>(<b>1</b>)</sup> = 3.8 × 10<sup>6</sup> M<sup>–1</sup> s<sup>–1</sup>) to <b>2</b> (<i>k</i><sub>on</sub><sup>(<b>2</b>)</sup> = 4.0 × 10<sup>5</sup> M<sup>–1</sup> s<sup>–1</sup>) and the inertness of <b>3</b>. …”
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