Search alternatives:
nn decrease » _ decrease (Expand Search), gy decreased (Expand Search), b1 decreased (Expand Search)
we decrease » _ decrease (Expand Search), teer decrease (Expand Search), use decreased (Expand Search)
a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
nn decrease » _ decrease (Expand Search), gy decreased (Expand Search), b1 decreased (Expand Search)
we decrease » _ decrease (Expand Search), teer decrease (Expand Search), use decreased (Expand Search)
a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
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Experimental and Computational Insight into the Mechanism of NO Binding to Ferric Microperoxidase. The Likely Role of Tautomerization to Account for the pH Dependence
Published 2021“…From the pH dependence of the second-order rate constant for NO binding (<i>k</i><sub>on</sub>), we determined individual rate constants characterizing forms <b>1</b>–<b>3</b>, revealing only a ca. 10-fold decrease in the NO binding rate on going from <b>1</b> (<i>k</i><sub>on</sub><sup>(<b>1</b>)</sup> = 3.8 × 10<sup>6</sup> M<sup>–1</sup> s<sup>–1</sup>) to <b>2</b> (<i>k</i><sub>on</sub><sup>(<b>2</b>)</sup> = 4.0 × 10<sup>5</sup> M<sup>–1</sup> s<sup>–1</sup>) and the inertness of <b>3</b>. …”
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