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    Syntheses of Pentanuclear Group 6 Iridium Clusters by Core Expansion of Tetranuclear Clusters with Ir(CO)<sub>2</sub>(η<sup>5</sup>‑C<sub>5</sub>Me<sub>4</sub>R) (R = H, Me) by Michael D. Randles (1902586)

    Published 2013
    “…Density functional theory (DFT) studies were employed to suggest the structure of <b>5</b>. The redox behavior of the new clusters was examined through cyclic voltammetry; all clusters exhibit oxidation and reduction processes (with respect to the resting state), with the oxidation processes being the more reversible, and increasingly so on decreasing Ir content of the clusters, replacing W by Mo, and increasing alkylation of the cyclopentadienyl ligands. …”