Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>‑Heterocyclic Carbene Complexes: A Combined X‑ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach by Mathis Benedikter (9726148)

“…The binding situation in the corresponding cationic complexes Mo­(<i>N</i>-2,6-Me₂C₆H₃)­(CHCMe₂Ph)­(NHC)­(OC­(CF₃)₃)⁺ B­(Ar^F)₄^– (NHC = IMes (<b>1</b>), IMesCl₂ (<b>2</b>), IMesMe₂ (<b>3</b>), and IMesH₂ (<b>4</b>) was compared to that of the analogous neutral Schrock catalyst Mo­(<i>N</i>-2,6-Me₂C₆H₃)­(CHCMe₂Ph)­((OC­(CF₃)₃))₂ (<b>5</b>). Single-crystal X-ray data were used as a starting point for the optimization of the geometries of the catalysts at the PBE0-D3BJ/def2-SVP level of theory; the obtained data were compared to those obtained from X-ray absorption (XAS) and emission spectroscopy (XES). …”

Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>‑Heterocyclic Carbene Complexes: A Combined X‑ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach by Mathis Benedikter (9726148)

“…The binding situation in the corresponding cationic complexes Mo­(<i>N</i>-2,6-Me₂C₆H₃)­(CHCMe₂Ph)­(NHC)­(OC­(CF₃)₃)⁺ B­(Ar^F)₄^– (NHC = IMes (<b>1</b>), IMesCl₂ (<b>2</b>), IMesMe₂ (<b>3</b>), and IMesH₂ (<b>4</b>) was compared to that of the analogous neutral Schrock catalyst Mo­(<i>N</i>-2,6-Me₂C₆H₃)­(CHCMe₂Ph)­((OC­(CF₃)₃))₂ (<b>5</b>). Single-crystal X-ray data were used as a starting point for the optimization of the geometries of the catalysts at the PBE0-D3BJ/def2-SVP level of theory; the obtained data were compared to those obtained from X-ray absorption (XAS) and emission spectroscopy (XES). …”

P-selectin mediates leukocyte rolling in the parietal peritoneum microcirculation. by Paulina M. Kowalewska (625078)

Optimal strategies for high <i>v</i>_<i>R</i> = 1.1386 and <i>T</i>_<i>R</i> = 0.1: (10% of population tested daily). by Mackenzie Dalton (14093874)

Loss of <i>Ramp2</i> leads to a proliferation defect in the labyrinth layer. by Mahita Kadmiel (4262311)

Image_1_Imatinib and Dasatinib Provoke Mitochondrial Dysfunction Leading to Oxidative Stress in C2C12 Myotubes and Human RD Cells.tiff by Jamal Bouitbir (3704710)

“…In C2C12 myoblasts, imatinib was membrane toxic at 50 µM and depleted the cellular ATP pool at 20 µM. …”

Evolution of R ratio (total consumer biomass change divided by NPP change) in regards to SST increase relative to reference period. by Vianney Guibourd de Luzinais (16871842)

“…<p>Where NPP is expected to decrease (a), or increase (b) under IPSL-SSP5-8.5 combination. …”

The change in spatial predictability for 6 pathogens plotted over time for outbreaks introduced to districts with a range of population densities. by John R. Giles (11084573)

Time-course studies for claudin-5 in mouse brain and CSF. by Ping-Sung Chiu (386303)

“…<p>Protein bands of (A) brain claudin-5 and (C) CSF claudin-5 from mice (n = 5) infected with <i>A. cantonensis</i>. β-actin and albumin were used as loading control. …”

The presence of consensus 5’SS motifs in various human loci. by Eliza S. Lee (715538)

“…<p>5’SS Motif depletion is based on the percent decrease between the observed number of motifs and the expected number based on tri-nucleotide frequencies (see <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0122743#pone.0122743.g006" target="_blank">Fig 6C</a>).…”

S1 Data - by Taher Mohammadizad (19786989)

“…The six HS treatments included birds exposed to a cyclic HS environment (34°C) for 8 h and were as follows: HSC, which consisted of the same basal diet with the recommended ITM levels; ACTM50 and ACTM100, which replaced the basal diet with 50% and 100% ACTM instead of ITM; ITM+ACTM12.5 and ITM+ACTM25, which involved adding extra ACTM to the ITM basal diet at 12.5% and 25%, respectively; and ITM125, which used 125% of the recommended levels of ITM in the basal diet. …”

Inflammatory cytokines and acute phase proteins in BALF and sera of infected mice. by Manoranjan Sahoo (189969)

Western blot analysis of myocardial IRF5 protein expression. by Hao Xu (6530)

<i>T</i>. <i>brucei</i> total lysates impair a hepatic infection by <i>P</i>. <i>yoelii</i>. by Adriana Temporão (7841300)

Dendritic arborization and spine geometry of hippocampal CA1 pyramidal neurons are impaired in <i>Cdkl5</i> -/Y mice. by Kosuke Okuda (5150393)

“…There are no significant differences in the mean numbers of basal and apical dendrites between two genotypes (A,I). The number of nodes (B,F), endings (C,G), intersections (E), and length (D,H) of basal dendrites are significantly decreased in <i>Cdkl5</i> -/Y mice. …”

Main outputs of the earth system models considered in the current study. by Vianney Guibourd de Luzinais (16871842)

Fig 1 - by Vianney Guibourd de Luzinais (16871842)

Syntheses, Crystal Structures, and Physical Properties of La₅Cu₆O₄S₇ and La₅Cu_6.33O₄S₇ by George H. Chan (2419864)

“…The optical band gap, <i>E</i>_g, of 2.0 eV was deduced from both diffuse reflectance spectra on a bulk sample of La₅Cu₆O₄S₇ and for the (010) crystal face of a La₅Cu_6.33O₄S₇ single crystal. …”

Syntheses, Crystal Structures, and Physical Properties of La₅Cu₆O₄S₇ and La₅Cu_6.33O₄S₇ by George H. Chan (2419864)

“…The optical band gap, <i>E</i>_g, of 2.0 eV was deduced from both diffuse reflectance spectra on a bulk sample of La₅Cu₆O₄S₇ and for the (010) crystal face of a La₅Cu_6.33O₄S₇ single crystal. …”

Image5_Utilizing multimodal mass spectrometry imaging for profiling immune cell composition and N-glycosylation across colorectal carcinoma disease progression.TIFF by Lyndsay E. A. Young (6329558)

“…Early detection through regular screening can result in a 90% 5-year survival rate for patients. However, unfortunately, only a fraction of CRC cases are identified at pre-invasive stages, allowing progression to occur silently over 10–15 years. …”