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teer decrease » greater decrease (Expand Search)
0 decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
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teer decrease » greater decrease (Expand Search)
0 decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
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Secondary Hypervalent I(III)···O Interactions: Synthesis and Structure of Hypervalent Complexes of Diphenyl-λ<sup>3</sup>-iodanes with 18-Crown-6
Published 2002“…Substitution of an electron-withdrawing group onto the <i>para</i> position of Ph<sub>2</sub>IBF<sub>4</sub> tends to increase in the complex stability. A linear Hammett relationship (ρ = 0.59) between log <i>K</i><sub>a</sub> and σ<sub>p</sub><sup>+</sup> values of substituents indicates that the diaryl-λ<sup>3</sup>-iodanes with electropositive iodine(III) interact more efficiently with 18C6. …”
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1317
Secondary Hypervalent I(III)···O Interactions: Synthesis and Structure of Hypervalent Complexes of Diphenyl-λ<sup>3</sup>-iodanes with 18-Crown-6
Published 2002“…Substitution of an electron-withdrawing group onto the <i>para</i> position of Ph<sub>2</sub>IBF<sub>4</sub> tends to increase in the complex stability. A linear Hammett relationship (ρ = 0.59) between log <i>K</i><sub>a</sub> and σ<sub>p</sub><sup>+</sup> values of substituents indicates that the diaryl-λ<sup>3</sup>-iodanes with electropositive iodine(III) interact more efficiently with 18C6. …”
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1318
Secondary Hypervalent I(III)···O Interactions: Synthesis and Structure of Hypervalent Complexes of Diphenyl-λ<sup>3</sup>-iodanes with 18-Crown-6
Published 2002“…Substitution of an electron-withdrawing group onto the <i>para</i> position of Ph<sub>2</sub>IBF<sub>4</sub> tends to increase in the complex stability. A linear Hammett relationship (ρ = 0.59) between log <i>K</i><sub>a</sub> and σ<sub>p</sub><sup>+</sup> values of substituents indicates that the diaryl-λ<sup>3</sup>-iodanes with electropositive iodine(III) interact more efficiently with 18C6. …”
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1319
Secondary Hypervalent I(III)···O Interactions: Synthesis and Structure of Hypervalent Complexes of Diphenyl-λ<sup>3</sup>-iodanes with 18-Crown-6
Published 2002“…Substitution of an electron-withdrawing group onto the <i>para</i> position of Ph<sub>2</sub>IBF<sub>4</sub> tends to increase in the complex stability. A linear Hammett relationship (ρ = 0.59) between log <i>K</i><sub>a</sub> and σ<sub>p</sub><sup>+</sup> values of substituents indicates that the diaryl-λ<sup>3</sup>-iodanes with electropositive iodine(III) interact more efficiently with 18C6. …”
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1320